Conversion−Temperature Diagram for a Palladium Membrane Reactor. Analysis of an Endothermic Reaction: Methane Steam Reforming
作者： Giuseppe Barbieri , Giuseppe Marigliano , Giovanni Perri , Enrico Drioli
DOI: 10.1021/IE0006211
关键词: Exothermic reaction 、 Thermodynamic equilibrium 、 Steam reforming 、 Isothermal process 、 Catalytic reforming 、 Thermodynamics 、 Reaction rate 、 Methane 、 Chemistry 、 Membrane reactor
摘要: An analysis of the conversion−temperature diagram for methane steam reforming is presented. A mathematical model a membrane reactor (MR) containing Pd-based with ideal behavior was developed to calculate temperature and species profiles. The comparison annular tubular configurations showed different MR performance because thermal effects. equilibrium system calculated, starting from method “reactors in series”. curve calculated as function sweep factor (I), defined ratio gas feed flow rates. existence region I delimited by adiabatic, isothermal, curves. Once I, molar ratio, oven were defined, reaction paths all MRs fell within region. This observed various values rates, thicknesses, overall heat transfer coefficients, geomet...
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sci-hub.se 参考文章(9)
Naotsugu Itoh, Wei-Chun Xu, Kenji Haraya, Basic experimental study on palladium membrane reactors Journal of Membrane Science. ,vol. 66, pp. 149- 155 ,(1992) , 10.1016/0376-7388(92)87005-I
Michael P. Harold, Chin Lee, Intermediate product yield enhancement with a catalytic inorganic membrane—II. Nonisothermal and integral operation in a back-mixed reactor Chemical Engineering Science. ,vol. 52, pp. 1923- 1939 ,(1997) , 10.1016/S0009-2509(97)00024-9
Ting Chia Huang, Teh Hua Tsai, Extraction of nickel(II) from sulfate solutions by bis(2-ethylhexyl)phosphoric acid dissolved in kerosene Industrial & Engineering Chemistry Research. ,vol. 28, pp. 1557- 1562 ,(1989) , 10.1021/IE00094A022
Giuseppe Barbieri, Vittorio Violante, Francesco P. Di Maio, Alessandra Criscuoli, Enrico Drioli, Methane Steam Reforming Analysis in a Palladium-Based Catalytic Membrane Reactor Industrial & Engineering Chemistry Research. ,vol. 36, pp. 3369- 3374 ,(1997) , 10.1021/IE970033W
Giuseppe Barbieri, Francesco P. Di Maio, Simulation of the methane steam re-forming process in a catalytic Pd-membrane reactor Industrial & Engineering Chemistry Research. ,vol. 36, pp. 2121- 2127 ,(1997) , 10.1021/IE9601615
N. Itoh, R. Govind, Combined oxidation and dehydrogenation in a palladium membrane reactor Industrial & Engineering Chemistry Research. ,vol. 28, pp. 1554- 1557 ,(1989) , 10.1021/IE00094A021
Michael Oertel, Johannes Schmitz, Walter Weirich, Ditmar Jendryssek-Neumann, Rudolf Schulten, Steam reforming of natural gas with intergrated hydrogen separation for hydrogen production Chemical Engineering & Technology. ,vol. 10, pp. 248- 255 ,(1987) , 10.1002/CEAT.270100130
Giuseppe S. Madia, Giuseppe Barbieri, Enrico Drioli, Theoretical and experimental analysis of methane steam reforming in a membrane reactor Canadian Journal of Chemical Engineering. ,vol. 77, pp. 698- 706 ,(1999) , 10.1002/CJCE.5450770411
Ying L. Becker, Anthony G. Dixon, William R. Moser, Yi Hua Ma, Modelling of ethylbenzene dehydrogenation in a catalytic membrane reactor Journal of Membrane Science. ,vol. 77, pp. 233- 244 ,(1993) , 10.1016/0376-7388(93)85072-5