Pauson-Khand reaction with allenic compounds I: Synthesis of 4-alkylidene-2-cyclopentenones

作者: Mohammed Ahmar , Frédéric Antras , Bernard Cazes

DOI: 10.1016/0040-4039(95)00735-U

关键词: Pauson–Khand reactionOrganic chemistryOxideChemistryIntermolecular force

摘要: Abstract The intermolecular cobalt-mediated cocyclisation of alkynes and allenes is efficiently promoted by N-methylmorpholine oxide at room temperature leads to 4-alkylidene-2-cyclopentenones.

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