Efficient and Convenient Deprotection of Thiocarbonyl to Carbonyl Compounds Using 3-Carboxypyridinium and 2,2′-Bipyridinium Chlorochromates in Solution, Dry Media, and under Microwave Irradiation

作者: Iraj Mohammadpoor-Baltork , Hamid Reza Memarian , Kiumars Bahrami , None

DOI: 10.1007/S00706-003-0095-0

关键词: Dry media reactionChemistryReagentMicrowave irradiationOrganic chemistryInorganic chemistry

摘要: A synthetic utility of 3-carboxypyridinium (CPCC) and 2,2′-bipyridinium (BPCC) chlorochromates in deprotection reactions is reported. Different types thioamides, thioureas, thiono esters, thioketones are deprotected to their corresponding carbonyl compounds with these reagents good excellent yields. The were carried out solution, under solvent-free conditions, microwave irradiation. results show that both the rates yields usually highest

参考文章(1)
Antony J. Hannaford, Peter W. G. Smith, Austin R. Tatchell, Brian S. Furniss, Vogel's Textbook of Practical Organic Chemistry ,(1996)