The catalytic effect of copper ions in the phenylation reaction of david and thieffry

作者: Derek H. R. Barton , Jean-Pierre Finet , Clotilde Pichon

DOI: 10.1039/C39860000065

关键词: Aliphatic compoundPhotochemistryInorganic chemistryBifunctionalCatalysisSolventCopperSolvent effectsChemistryDiolMolecule

摘要: Several types of bifunctional molecules are smoothly phenylated by triphenylbismuth diacetate in a reaction which has an intduction period, curious solvent dependence, and the need for illumination; however, addition small amount Cu(OAc)2 removes all these limitations accelerates greatly reaction.

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