Anion-templated 2D frameworks from hexahydroxytriphenylene
作者： Mahbod Morshedi , Anthony C. Willis , Nicholas G. White
DOI: 10.1039/C6CE00297H
关键词: Hydrogen bond 、 Polymer chemistry 、 Ion 、 Organic chemistry 、 Chemistry 、 General Materials Science 、 General chemistry 、 Condensed matter physics
摘要: Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H⋯anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals HHTP and tetraalkylammonium·anion salts are obtained, which have layered structure. When HSO4− was used as anion, an unprecedented methylation reaction observed giving crystals containing the methylsulfate anion (MeOSO3−).
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