Ion-pairing in polyether solid electrolytes and its influence on ion transport

作者: B.L. Papke , R. Dupon , M.A. Ratner , D.F. Shriver

DOI: 10.1016/0167-2738(81)90346-5

关键词: Fast ion conductorEthylene oxideConductivityIonic conductivitySalt (chemistry)StoichiometryInorganic chemistryIonAlkali metalChemistry

摘要: Abstract Vibrational spectroscopic and conductivity data are presented for complexes of NaBF 4 NaBH with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the complex but not complex. As a result ionic is considerably lower complex, due to trapping mobile sodium cations by anion. The effect salt stoichiometry on behavior also reported.

参考文章(4)
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