作者: A. Bianconi , S. Della Longa , C. Li , M. Pompa , A. Congiu-Castellano
DOI: 10.1103/PHYSREVB.44.10126
关键词: Inorganic compound 、 Continuum (set theory) 、 Condensed matter physics 、 Electronic band structure 、 Excited state 、 XANES 、 Electronic structure 、 Physics 、 Bound state 、 Crystallography 、 Oscillator strength
摘要: The linearly polarized Cu {ital L}{sub 3}-edge x-ray-absorption near-edge structure (XANES) of Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}} has been measured and the spectra are interpreted by full multiple-scattering approach in real space. over a range 20 eV can be predicted terms one-electron dipole ({Delta}{ital l}=+1) transition 2{ital p}{r arrow}{epsilon}{ital d}, probing unoccupied d}-like ({ital l}=2) density states projected on site with orbital angular momentum m}{sub l}}=0, 1 {bold E}( ){ital z} spectra, l}}=2, 1, 0 E}{perpendicular}{ital c} spectra. oscillator strength for allowed transitions l}={minus}1) arrow}{var epsilon}{ital s} is shown to factor 100 weaker than arrow}3{ital d} transitions. Coulomb interaction final state between p} core hole excited 3{ital electron found 5.5 forming bound below continuum threshold, well-known 3} white line. On contrary, induces nearly rigid redshift about high-energy conduction bands.