Biphenyl hydrogenation over supported transition metal catalysts under supercritical carbon dioxide solvent
作者： Norihito Hiyoshi , Chandrashekhar V. Rode , Osamu Sato , Masayuki Shirai
DOI: 10.1016/J.APCATA.2005.04.021
关键词: Chemistry 、 Biphenyl 、 Hydrocarbon 、 Hydrogen storage 、 Inorganic chemistry 、 Organic chemistry 、 Catalyst support 、 Supercritical carbon dioxide 、 Catalysis 、 Rhodium 、 Carbon
摘要: Catalytic hydrogenation of biphenyl to bicyclohexyl, an organic hydrogen storage medium, was examined over supported transition metal catalysts in supercritical carbon dioxide solvent. The yield of bicyclohexyl was almost 100% over the charcoal-supported rhodium (Rh/C) and ruthenium (Ru/C) catalysts at the temperature of 323K, which was much lower than that required for biphenyl hydrogenation in organic solvents (573K). The initial activity was higher over the Rh/C catalyst, while the initial selectivity to bicyclohexyl was higher over …
elsevier.com
sci-hub.se 参考文章(11)
Philip G. Jessop, Walter Leitner, Chemical synthesis using supercritical fluids Wiley-VCH. ,(1999)
G. C. Bond, Vladimír Ponec, Catalysis by metals and alloys Elsevier. ,(1995)
Chiaki Shinohara, Satoshi Kawakami, Toshihiro Moriga, Hiromu Hayashi, Shinya Hodoshima, Yasukazu Saito, Shigeru Sugiyama, Local structure around platinum in Pt/C catalysts employed for liquid-phase dehydrogenation of decalin in the liquid-film state under reactive distillation conditions Applied Catalysis A-general. ,vol. 266, pp. 251- 255 ,(2004) , 10.1016/J.APCATA.2004.02.014
Nobuko Kariya, Atsushi Fukuoka, Tadashi Utagawa, Masashi Sakuramoto, Yasushi Goto, Masaru Ichikawa, Efficient hydrogen production using cyclohexane and decalin by pulse-spray mode reactor with Pt catalysts Applied Catalysis A-general. ,vol. 247, pp. 247- 259 ,(2003) , 10.1016/S0926-860X(03)00104-2
Chandrashekhar V. Rode, Uday D. Joshi, Osamu Sato, Masayuki Shirai, Catalytic ring hydrogenation of phenol under supercritical carbon dioxide Chemical Communications. pp. 1960- 1961 ,(2003) , 10.1039/B304344D
Norihito Hiyoshi, Chandrashekhar V. Rode, Osamu Sato, Masayuki Shirai, Hydrogenation of Biphenyl over Charcoal-supported Metal Catalysts under Supercritical Carbon Dioxide Journal of The Japan Petroleum Institute. ,vol. 47, pp. 410- 411 ,(2004) , 10.1627/JPI.47.410
Yuguo Wang, Naresh Shah, Gerald P. Huffman, Pure Hydrogen Production by Partial Dehydrogenation of Cyclohexane and Methylcyclohexane over Nanotube-Supported Pt and Pd Catalysts Energy & Fuels. ,vol. 18, pp. 1429- 1433 ,(2004) , 10.1021/EF049959O
M. Koussathana, D. Vamvouka, H. Economou, X. Verykios, Slurry-phase hydrogenation of aromatic compounds over supported noble metal catalysts Applied Catalysis. ,vol. 77, pp. 283- 301 ,(1991) , 10.1016/0166-9834(91)80072-5
S Hodoshima, Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle International Journal of Hydrogen Energy. ,vol. 28, pp. 1255- 1262 ,(2003) , 10.1016/S0360-3199(02)00250-1
Takafumi Sato, Chandrashekhar V. Rode, Osamu Sato, Masayuki Shirai, Hydrogenation of isophorone with noble metal catalysts in supercritical carbon dioxide Applied Catalysis B-environmental. ,vol. 49, pp. 181- 185 ,(2004) , 10.1016/J.APCATB.2003.12.010