Phase transition, piezoelectric, and multiferroic properties of La(Co0.5Mn0.5)O3‐modified BiFeO3–BaTiO3 lead‐free ceramics
作者： Lingling Luo , Na Jiang , Xiao Zou , Dongliang Shi , Ting Sun
关键词: Materials science 、 Condensed matter physics 、 Piezoelectricity 、 Phase transition 、 Curie temperature 、 Crystal structure 、 Multiferroics 、 Orthorhombic crystal system 、 Phase boundary 、 Ferroelectricity
摘要: (0.75–x)BiFeO3−0.25BaTiO3−xLa(Co0.5Mn0.5)O3 + 1 mol% MnO2 lead-free ceramics (x = 0–0.10) were synthesized by a conventional solid-state reaction route and the effects of La(Co0.5Mn0.5)O3 on phase transition, piezoelectric, ferroelectric, multiferroic properties investigated. The can be well sintered at 960 °C for 2 h. After addition La(Co0.5Mn0.5)O3, crystal structure is transformed from rhombohedral (space group R3c) to orthorhombic symmetry Amm2), morphotropic boundary (MPB) phases formed x = 0.01–0.03. dielectric peak was found become diffusive with increasing x. x = 0–0.03 possess strong piezoelectricity d33 95–108 pC N−1, ferroelectricity Pr 2.2–18.1 μC cm−2, considerable magnetoelectric coefficient 372–672 mV/cmOe, high Curie temperature 523–659 °C, showing potential applications in devices.
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M. Abplanalp, D. Barošová, P. Bridenbaugh, J. Erhart, J. Fousek, P. Günter, J. Nosek, M. Šulc, Scanning force microscopy of domain structures in Pb(Zn1/3Nb2/3)O3-8% PbTiO3 and Pb(Mg1/3Nb2/3)O3-29% PbTiO3 Journal of Applied Physics. ,vol. 91, pp. 3797- 3805 ,(2002) , 10.1063/1.1446655
VB Naik, R Mahendiran, None, Magnetic and magnetoelectric studies in pure and cation doped BiFeO3 Solid State Communications. ,vol. 149, pp. 754- 758 ,(2009) , 10.1016/J.SSC.2009.03.003
Qingyu Xu, Shengqiang Zhou, D. Wu, Marc Uhlarz, Y. K. Tang, Kay Potzger, M. X. Xu, Heidemarie Schmidt, Cluster spin glass behavior in Bi(Fe0.95Co0.05)O3 Journal of Applied Physics. ,vol. 107, pp. 093920- ,(2010) , 10.1063/1.3406150
Shan-Tao Zhang, Yi Zhang, Ming-Hui Lu, Chao-Ling Du, Yan-Feng Chen, Zhi-Guo Liu, Yong-Yuan Zhu, Nai-Ben Ming, X. Q. Pan, Substitution-induced phase transition and enhanced multiferroic properties of Bi1−xLaxFeO3 ceramics Applied Physics Letters. ,vol. 88, pp. 162901- ,(2006) , 10.1063/1.2195927
R S Devan, D R Dhakras, T G Vichare, A S Joshi, S R Jigajeni, Yuan-Ron Ma, B K Chougule, Li0.5Co0.75Fe2O4 + BaTiO3 particulate composites with coupled magnetic-electric properties Journal of Physics D. ,vol. 41, pp. 105010- ,(2008) , 10.1088/0022-3727/41/10/105010
Qin Zhou, Changrong Zhou, Huabin Yang, Guohua Chen, Weizhou Li, Hua Wang, Dielectric, Ferroelectric, and Piezoelectric Properties of Bi(Ni1/2Ti1/2)O3‐Modified BiFeO3–BaTiO3 Ceramics with High Curie Temperature Journal of the American Ceramic Society. ,vol. 95, pp. 3889- 3893 ,(2012) , 10.1111/J.1551-2916.2012.05387.X
Yongxing Wei, Xiaotao Wang, Jintao Zhu, Xiaoli Wang, Jiangjiang Jia, Dielectric, Ferroelectric, and Piezoelectric Properties of BiFeO3–BaTiO3 Ceramics Journal of the American Ceramic Society. ,vol. 96, pp. 3163- 3168 ,(2013) , 10.1111/JACE.12475
Dong-liang Shi, Kwok Ho Lam, Kun Li, LPF-doped core–shell structure based CFO/PLZT 0–3 magnetoelectric composite ceramics Journal of Alloys and Compounds. ,vol. 617, pp. 485- 490 ,(2014) , 10.1016/J.JALLCOM.2014.08.016
Takaaki Tsurumi, Hiroshige Adachi, Hirofumi Kakemoto, Satoshi Wada, Youichi Mizuno, Hirokazu Chazono, Hiroshi Kishi, Dielectric Properties of BaTiO3-Based Ceramics under High Electric Field Japanese Journal of Applied Physics. ,vol. 41, pp. 6929- 6933 ,(2002) , 10.1143/JJAP.41.6929
XiaoMing Chen, XuXu Gong, TingNan Li, Yuan He, Peng Liu, None, Microstructure, dielectric and ferroelectric properties of (1−x)(0.94Bi0.5Na0.5TiO3–0.06BaTiO3)–xBiFeO3 lead-free ceramics synthesized via a high energy ball milling method Journal of Alloys and Compounds. ,vol. 507, pp. 535- 541 ,(2010) , 10.1016/J.JALLCOM.2010.08.012