Effect of structure of the electrical performance of gas diffusion electrodes for metal air batteries

作者: Mario Maja , Claudio Orecchia , Morela Strano , Paolo Tosco , Marco Vanni

DOI: 10.1016/S0013-4686(00)00601-0

关键词: Gaseous diffusionInorganic chemistryChemical engineeringPorosimetryElectrolyteChemistryDielectric spectroscopyElectrocatalystElectrochemistryElectrodeCarbon

摘要: The effects of different commercial carbon powders (Vulcan XC72R, Black Pearls 3700 and Shawiningan Black), on the performance double-layered gas diffusion electrodes are reported. active mass was catalysed with cobalt tetramethoxyphenylporphyrin. Various techniques such as impregnation, permeation, porosimetry, SEM observations impedance spectroscopy were used to characterise structure electrodes. electrochemical behaviour determined by means polarisation curves in alkaline electrolyte. catalytic activity physical characteristics material strongly affect life results significantly contribute proper selection materials optimisation electrode manufacturing technology. Besides estimation some structural parameters enables correct simulation behaviour.

参考文章(15)
Philip Crosbie Carman, Flow of gases through porous media ,(1956)
L. Giorgi, E. Antolini, A. Pozio, E. Passalacqua, Influence of the PTFE content in the diffusion layer of low-Pt loading electrodes for polymer electrolyte fuel cells Electrochimica Acta. ,vol. 43, pp. 3675- 3680 ,(1998) , 10.1016/S0013-4686(98)00125-X
M. Viitanen, M.J. Lampinen, A mathematical model and optimization of the structure for porous air electrodes Journal of Power Sources. ,vol. 32, pp. 207- 231 ,(1990) , 10.1016/0378-7753(90)87015-J
Klaus Tomantschger, Karl V. Kordesch, Structural analysis of alkaline fuel cell electrodes and electrode materials Journal of Power Sources. ,vol. 25, pp. 195- 214 ,(1989) , 10.1016/0378-7753(89)80004-7
Jean-Pierre Candy, Pierre Fouilloux, Michel Keddam, Hisasi Takenouti, The characterization of porous electrodes by impedance measurements Electrochimica Acta. ,vol. 26, pp. 1029- 1034 ,(1981) , 10.1016/0013-4686(81)85072-4
A. Kaisheva, I. Iliev, S. Gamburzev, Comparative methods for the estimation of the activity and the transport hindrances of air gas-diffusion electrodes Journal of Power Sources. ,vol. 13, pp. 181- 195 ,(1984) , 10.1016/0378-7753(84)80002-6
P. Delahay, Ashok K. Vijh, Advances in Electrochemistry and Electrochemical Engineering Journal of The Electrochemical Society. ,vol. 117, ,(1964) , 10.1149/1.2407311
H. Keiser, K.D. Beccu, M.A. Gutjahr, Abschätzung der porenstruktur poröser elektroden aus impedanzmessungen Electrochimica Acta. ,vol. 21, pp. 539- 543 ,(1976) , 10.1016/0013-4686(76)85147-X