Nonplanar Aromatic Compounds. 6. [2]Paracyclo[2](2,7)pyrenophane. A Novel Strained Cyclophane and a First Step on the Road to a “Vögtle” Belt†
作者： Graham J. Bodwell , David O. Miller , Rudolf J. Vermeij
DOI: 10.1021/OL016053I
关键词: Cyclophane 、 Crystallography 、 Valence (chemistry) 、 Pyrene 、 Stereochemistry 、 Pyrenophane 、 Bent molecular geometry 、 Benzene 、 Chemistry
摘要: A benzene ring nestled into the concave face of a bent pyrene characterizes title compound in crystal. The synthesis this was accomplished using valence isomerization−dehydrogenation (VID) method and marks official launch our journey en route to aromatic belts first proposed by Prof. Vogtle.
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