Green and Practical Oxidative Deoximation of Oximes to Ketones or Aldehydes with Hydrogen Peroxide/Air by Organoselenium Catalysis
作者： Xiaobi Jing , Dandan Yuan , Lei Yu
关键词: Oxidative phosphorylation 、 Organic chemistry 、 Hydrogen peroxide 、 Chemistry 、 Catalysis 、 Selenium
摘要: Organoselenium-catalyzed oxidative deoximations afforded ketones and aldehydes under mild conditions. The reactions employ hydrogen peroxide air as clean oxidants lead to a waste-free metal-free deprotection protocol for carbonyl protection strategies well the green synthesis of aldehydes. mechanisms this interesting organoselenium-catalyzed reaction have been investigated by control experiments selenium 77 nuclear magnetic resonance (77Se NMR) tests. This novel largely expands application scope organoselenium catalysis.
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