Preparation and property of soluble azobenzene-containing substituted poly(1-alkyne)s optical limiting materials
作者： Shouchun Yin , Hongyao Xu , Xinyan Su , Lei Wu , Yinglin Song
DOI: 10.1016/J.DYEPIG.2006.07.013
关键词: Azobenzene 、 Nonlinear optics 、 Photochemistry 、 Catalysis 、 Chemistry 、 Alkyne 、 Fourier transform infrared spectroscopy 、 Chromophore 、 Proton NMR 、 Polyacetylene 、 Polymer chemistry
摘要: Abstract Two novel poly(1-alkyne)s containing azobenzene nonlinear optical chromophoric group, poly(4-(4-[4-( n -dodecyloxy)phenylazophenyl]carbonyl)oxy-1-butyne) (P 1 ) and poly(11-(4-[4-( -dodecyloxy)phenylazophenyl]carbonyl)oxy-1-undecyne) 2 ), were synthesized by [Rh(nbd)Cl] –Et 3 N catalysts characterized FTIR, H NMR, GPC UV–vis techniques. Their limiting properties investigated using 8 ns pulse at 532 nm. The results show that these soluble functional possess good large properties.
core.ac.uk
elsevier.com
sci-hub.se 参考文章(27)
Takeyuki Sone, Ryuichi Asako, Toshio Masuda, Masayoshi Tabata, Tatsuo Wada, Hiroyuki Sasabe, Polymerization of o-Trifluoromethyl(phenylacetylene) Initiated by [Rh(norbornadiene)Cl]2 and MoOCl4−n-Bu4Sn−EtOH Catalysts. Formation of Order and Disorder Trans Sequences Macromolecules. ,vol. 34, pp. 1586- 1592 ,(2001) , 10.1021/MA000489G
Shouchun Yin, Hongyao Xu, Wenfang Shi, Yachen Gao, Yinlin Song, Jacky Wing Yip Lam, Ben Zhong Tang, Synthesis and optical properties of polyacetylenes containing nonlinear optical chromophores Polymer. ,vol. 46, pp. 7670- 7677 ,(2005) , 10.1016/J.POLYMER.2005.05.118
Ahmet Giz, Huceste Çatalgil-Giz, Alina Alb, Jean-Luc Brousseau, Wayne F. Reed, Kinetics and Mechanisms of Acrylamide Polymerization from Absolute, Online Monitoring of Polymerization Reaction Macromolecules. ,vol. 34, pp. 1180- 1191 ,(2001) , 10.1021/MA000815S
Ryoji Nomura, S. M. Abdul Karim, Hirotake Kajii, Rahmat Hidayat, Katsumi Yoshino, Toshio Masuda, Metathesis Polymerization of 9-(10-Hexoxycarbonyl)anthrylacetylene. A Route to a Widely Conjugated Polyacetylene with Excellent Stability and Solubility Macromolecules. ,vol. 33, pp. 4313- 4315 ,(2000) , 10.1021/MA0003708
Eiji Yashima, Teruyuki Matsushima, Yoshio Okamoto, Chirality Assignment of Amines and Amino Alcohols Based on Circular Dichroism Induced by Helix Formation of a Stereoregular Poly((4-carboxyphenyl)acetylene) through Acid−Base Complexation Journal of the American Chemical Society. ,vol. 119, pp. 6345- 6359 ,(1997) , 10.1021/JA964470Y
Guangzheng Gao, Fumio Sanda, Toshio Masuda, Copolymerization of Chiral Amino Acid-Based Acetylenes and Helical Conformation of the Copolymers Macromolecules. ,vol. 36, pp. 3938- 3943 ,(2003) , 10.1021/MA021432S
W.-S. Fann, S. Benson, J. M. J. Madey, S. Etemad, G. L. Baker, F. Kajzar, Spectrum of chi (3)(-3 omega; omega, omega, omega ) in polyacetylene: An application of free-electron laser in nonlinear optical spectroscopy. Physical Review Letters. ,vol. 62, pp. 1492- 1495 ,(1989) , 10.1103/PHYSREVLETT.62.1492
Ben Zhong Tang, Hongyao Xu, Preparation, Alignment, and Optical Properties of Soluble Poly(phenylacetylene)-Wrapped Carbon Nanotubes† Macromolecules. ,vol. 32, pp. 2569- 2576 ,(1999) , 10.1021/MA981825K
Kazunari Nanjo, S. M. Abdul Karim, Ryoji Nomura, Tatsuo Wada, Hiroyuki Sasabe, Toshio Masuda, Synthesis and properties of poly(1‐naphthylacetylene) and poly(9‐anthrylacetylene) Journal of Polymer Science Part A. ,vol. 37, pp. 277- 282 ,(1999) , 10.1002/(SICI)1099-0518(19990201)37:3<277::AID-POLA4>3.0.CO;2-Q
M. Falconieri, R. D’Amato, A. Furlani, M.V. Russo, Z-scan measurements of third-order optical non-linearities in poly(phenylacetylenes) Synthetic Metals. ,vol. 124, pp. 217- 219 ,(2001) , 10.1016/S0379-6779(01)00455-6