A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

作者: Jing Zhang , Shiguo Han , Xitao Liu , Zhenyue Wu , Chengmin Ji

DOI: 10.1039/C8CC02496K

关键词: Quadratic equationNonlinear opticalMaterials scienceCondensed matter physicsZigzagPerovskite (structure)

摘要: We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2− polyanionic zigzag chains, which shows above-room-temperature switching quadratic nonlinear optical (NLO) properties induced by the unique order–disorder conformational changes organic cation.

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