Preparation of cotton linter nanowhiskers by high-pressure homogenization process and its application in thermoplastic starch

作者: N. R. Savadekar , V. S. Karande , N. Vigneshwaran , P. G. Kadam , S. T. Mhaske

DOI: 10.1007/S13204-014-0316-3

关键词: HomogenizerOxygen permeabilityDifferential scanning calorimetryComposite materialScanning electron microscopeMaterials sciencePolymerNanocompositeThermoplasticUltimate tensile strength

摘要: The present work deals with the preparation of cotton linter nanowhiskers (CLNW) by acid hydrolysis and subsequent processing in a high-pressure homogenizer. Prepared CLNW were then used as reinforcing material thermoplastic starch (TPS), an aim to improve its performance properties. Concentration was varied 0, 1, 2, 3, 4 5 wt% TPS. TPS/CLNW nanocomposite films prepared solution-casting process. characterized tensile, differential scanning calorimetry, electron microscopy (SEM), water vapor permeability (WVP), oxygen (OP), X-ray diffraction light transmittance 3 wt% CLNW-loaded TPS demonstrated 88 % improvement tensile strength compared pristine polymer film; whereas, WVP OP decreased 90 92 %, respectively, which is highly appreciable quantity added. DSC thermograms did not show any significant effect on melting temperature Light (Tr) value increased content CLNW. Better interaction between TPS, caused due hydrophilic nature both materials, uniform distribution prime reason for properties observed at loading However, seen have formed agglomerates higher concentration determined from SEM analysis. These can potential use food pharmaceutical packaging applications.

参考文章(36)
Maren Grunert, William T. Winter, Nanocomposites of Cellulose Acetate Butyrate Reinforced with Cellulose Nanocrystals Journal of Polymers and The Environment. ,vol. 10, pp. 27- 30 ,(2002) , 10.1023/A:1021065905986
Ingvild Kvien, Junji Sugiyama, Martin Votrubec, Kristiina Oksman, Characterization of starch based nanocomposites Journal of Materials Science. ,vol. 42, pp. 8163- 8171 ,(2007) , 10.1007/S10853-007-1699-2
Panya Wongpanit, Neeracha Sanchavanakit, Prasit Pavasant, Tanom Bunaprasert, Yasuhiko Tabata, Ratana Rujiravanit, Preparation and characterization of chitin whisker-reinforced silk fibroin nanocomposite sponges European Polymer Journal. ,vol. 43, pp. 4123- 4135 ,(2007) , 10.1016/J.EURPOLYMJ.2007.07.004
S. J. Eichhorn, A. Dufresne, M. Aranguren, N. E. Marcovich, J. R. Capadona, S. J. Rowan, C. Weder, W. Thielemans, M. Roman, S. Renneckar, W. Gindl, S. Veigel, J. Keckes, H. Yano, K. Abe, M. Nogi, A. N. Nakagaito, A. Mangalam, J. Simonsen, A. S. Benight, A. Bismarck, L. A. Berglund, T. Peijs, Review: current international research into cellulose nanofibres and nanocomposites Journal of Materials Science. ,vol. 45, pp. 1- 33 ,(2010) , 10.1007/S10853-009-3874-0
A.J.F Carvalho, A.E Job, N Alves, A.A.S Curvelo, A Gandini, Thermoplastic starch/natural rubber blends Carbohydrate Polymers. ,vol. 53, pp. 95- 99 ,(2003) , 10.1016/S0144-8617(03)00005-5
Andrea Sorrentino, Giuliana Gorrasi, Vittoria Vittoria, Potential perspectives of bio-nanocomposites for food packaging applications Trends in Food Science and Technology. ,vol. 18, pp. 84- 95 ,(2007) , 10.1016/J.TIFS.2006.09.004
My Ahmed Said Azizi Samir, Fannie Alloin, Alain Dufresne, None, Review of Recent Research into Cellulosic Whiskers, Their Properties and Their Application in Nanocomposite Field Biomacromolecules. ,vol. 6, pp. 612- 626 ,(2005) , 10.1021/BM0493685
Stephanie Beck-Candanedo, Maren Roman, Derek G. Gray, Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules. ,vol. 6, pp. 1048- 1054 ,(2005) , 10.1021/BM049300P
Maria D. Sanchez-Garcia, Jose M. Lagaron, On the use of plant cellulose nanowhiskers to enhance the barrier properties of polylactic acid Cellulose. ,vol. 17, pp. 987- 1004 ,(2010) , 10.1007/S10570-010-9430-X