Tetranuclear zinc(II)-oxy (benzothiazole)-2-thiolate aggregate and copper(I) phenylthiolate aggregate
作者： Abir Goswami , Nithi Phukan , Jubaraj Bikash Baruah
DOI: 10.1080/23312009.2015.1060046
关键词: Copper 、 Hydrothermal circulation 、 Zinc 、 Polymer chemistry 、 Benzothiazole 、 Zinc ion 、 Inorganic chemistry 、 Iodide 、 Ligand 、 Zinc nitrate 、 Chemistry
摘要: AbstractA tetranuclear zinc-oxy (benzothiazole)-2-thiolate aggregate whose structure has a C3-axis passing through ZnO unit relating three other zinc ions and copper(I) phenylthiolate having each thiphenolate ligand bridging copper are reported. These aggregates were prepared by hydrothermal reactions of 2,2′-dithiobis-(benzothiazole) with nitrate or iodide, respectively. The reaction passed in situ abstraction oxy from moisture to form Zn4O core holding six 2-benzothiazolethiolate ligands, during the formation aggregate, cleavage S–S bond took place. Whereas, an formed self-assembling was after extensive degradation solvothermal reaction.
core.ac.uk
cogentoa.com参考文章(20)
Ian G Dance, Graham A Bowmaker, George R Clark, Jeffrey K Seadon, The formation and crystal and molecular structures of hexa(μ-organothiolato)tetracuprate(I) cage dianions: bis-(tetramethylammonium)hexa-(μ-methanethiolato)tetracuprate(I) and two polymorphs of bis(tetramethylammonium)hexa-(μ-benzenethiolato)-tetracuprate(I) Polyhedron. ,vol. 2, pp. 1031- 1043 ,(1983) , 10.1016/S0277-5387(00)81450-3
Renzo Bertoncello, Marco Bettinelli, Maurizio Casarin, Antonino Gulino, Eugenio Tondello, Andrea Vittadini, Hexakis(acetato)oxotetrazinc, a well-tailored molecular model of zinc oxide. An experimental and theoretical investigation of the electronic structure of Zn4O(acetate)6 and ZnO by means of UV and x-ray photoelectron spectroscopies and first principle local density molecular cluster calculations Inorganic Chemistry. ,vol. 31, pp. 1558- 1565 ,(1992) , 10.1021/IC00035A008
Chengyang Yue, Chunfeng Yan, Rui Feng, Mingyan Wu, Lian Chen, Feilong Jiang, Maochun Hong, A Polynuclear d10−d10 Metal Complex with Unusual Near-Infrared Luminescence and High Thermal Stability Inorganic Chemistry. ,vol. 48, pp. 2873- 2879 ,(2009) , 10.1021/IC801840G
Somnath Dey, Alexander Efimov, Chandan Giri, Kari Rissanen, Helge Lemmetyinen, Electronic Structure Manipulation of (Benzothiazole)zinc Complexes: Synthesis, Optical and Electrochemical Studies of 5‐Substituted Derivatives European Journal of Organic Chemistry. ,vol. 2011, pp. 6226- 6232 ,(2011) , 10.1002/EJOC.201100186
Kim J Yaghi, OM, O'Keeffe, M, Ockwig NW, Chae, HK, Eddaoudi M, Reticular synthesis and the design of new materials Nature. ,vol. 423, pp. 705- 714 ,(2003) , 10.1038/NATURE01650
J.A. Schuerman, F.R. Fronczek, J. Selbin, Crystal and molecular structures of tetranuclear metal clusters of copper(I) trithioperoxybenzoates Inorganica Chimica Acta. ,vol. 148, pp. 177- 183 ,(1988) , 10.1016/S0020-1693(00)87498-8
Hyungphil Chun, Heejin Jung, Targeted Synthesis of a Prototype MOF Based on Zn4(O)(O2C)6 Units and a Nonlinear Dicarboxylate Ligand Inorganic Chemistry. ,vol. 48, pp. 417- 419 ,(2009) , 10.1021/IC801906E
Wei Wei, Mingyan Wu, Qiang Gao, Qingfu Zhang, Yougui Huang, Feilong Jiang, Maochun Hong, A novel supramolecular tetrahedron assembled from tetranuclear copper(I) cluster molecules via aryl embrace interactions. Inorganic Chemistry. ,vol. 48, pp. 420- 422 ,(2009) , 10.1021/IC801972E
Sándor B. Ötvös, Ottó Berkesi, Tamás Körtvélyesi, István Pálinkó, Synthesis and spectroscopic and computational characterization of Zn4O(alicyclic or aromatic carboxylate)6 complexes as potential MOF precursors. Inorganic Chemistry. ,vol. 49, pp. 4620- 4625 ,(2010) , 10.1021/IC100205N
Stephen L. Lawton, Wayne J. Rohrbaugh, George T. Kokotailo, Crystal and molecular structure of the tetranuclear metal cluster complex copper(I) O,O'-diisopropylphosphorodithioate,Cu4[(iso-PrO)2PS2]4 Inorganic Chemistry. ,vol. 11, pp. 612- 618 ,(1972) , 10.1021/IC50109A039