Green oil poisoning of a Pd/a1203 acetylene hydrogenation catalyst
作者： A. Sárkány , A.H. Weiss , T. Szilágyi , P. Sándor , L. Guczi
DOI: 10.1016/S0166-9834(00)81674-7
关键词: Inorganic chemistry 、 Infrared 、 Organic chemistry 、 Catalysis 、 Acetylene hydrogenation 、 Product distribution 、 Chemistry 、 Composition (visual arts)
摘要: The composition and deactivation effect of green oil on a Pd/A1203 catalyst (ICI 38-1) in the hydrogenation tail-end acetylene-ethylene mixture are discussed. Infrared NMR measurements confirmed presence carboxylic acids oil. poisoned acetylene sites but product distribution pattern was not greatly affected.
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