Electrosprayed graphene decorated with ZnO nanoparticles for supercapacitors

作者: Edmund Samuel , Priyanka U Londhe , Bhavana Joshi , Min-Woo Kim , Karam Kim

DOI: 10.1016/J.JALLCOM.2017.12.320

关键词: CapacitanceNanocompositeComposite numberMaterials scienceScanning electron microscopeGrapheneSupercapacitorDiffractionChemical engineeringPower densityMechanical engineeringMaterials ChemistryMechanics of MaterialsMetals and Alloys

摘要: Abstract A binder-free nanocomposite consisting of ZnO nanoparticles (NPs) grown directly on graphene sheets by electrospraying was fabricated for use as an electrode material in supercapacitors. The optimal concentrations and NPs were determined from the capacitive characteristics composite. Scanning electron microscopy confirmed that grew a uniformly distributed manner they exhibited negligible agglomeration. Further, X-ray diffraction analysis growth preferentially oriented along (100) plane ZnO/graphene symmetric supercapacitor using this composite energy density 67 mWh·cm−3 power 6000 mW·cm−3. also showed good long-term cycling performance, retaining 90% its capacitance after 1000 galvanostatic charge/discharge cycles.

参考文章(41)
Jagruti S. Suroshe, Shivram S. Garje, Capacitive behaviour of functionalized carbon nanotube/ZnO composites coated on a glassy carbon electrode Journal of Materials Chemistry. ,vol. 3, pp. 15650- 15660 ,(2015) , 10.1039/C5TA01725D
Xing Sun, Qiang Li, Yinong Lü, Yuanbing Mao, Three-dimensional ZnO@MnO2 core@shell nanostructures for electrochemical energy storage. Chemical Communications. ,vol. 49, pp. 4456- 4458 ,(2013) , 10.1039/C3CC41048J
Ting Lu, Likun Pan, Haibo Li, Guang Zhu, Tian Lv, Xinjuan Liu, Zhuo Sun, Ting Chen, Daniel H.C. Chua, Microwave-assisted synthesis of graphene–ZnO nanocomposite for electrochemical supercapacitors Journal of Alloys and Compounds. ,vol. 509, pp. 5488- 5492 ,(2011) , 10.1016/J.JALLCOM.2011.02.136
V. Stavila, A. A. Talin, M. D. Allendorf, MOF-based electronic and opto-electronic devices. Chemical Society Reviews. ,vol. 43, pp. 5994- 6010 ,(2014) , 10.1039/C4CS00096J
Chi-Chang Hu, Kuo-Hsin Chang, Ming-Champ Lin, Yung-Tai Wu, Design and Tailoring of the Nanotubular Arrayed Architecture of Hydrous RuO2 for Next Generation Supercapacitors Nano Letters. ,vol. 6, pp. 2690- 2695 ,(2006) , 10.1021/NL061576A
Yanping Zhang, Haibo Li, Likun Pan, Ting Lu, Zhuo Sun, Capacitive behavior of graphene–ZnO composite film for supercapacitors Journal of Electroanalytical Chemistry. ,vol. 634, pp. 68- 71 ,(2009) , 10.1016/J.JELECHEM.2009.07.010
Z.J. Li, B.C. Yang, S.R. Zhang, C.M. Zhao, Graphene oxide with improved electrical conductivity for supercapacitor electrodes Applied Surface Science. ,vol. 258, pp. 3726- 3731 ,(2012) , 10.1016/J.APSUSC.2011.12.015
D Kalpana, KS Omkumar, S Suresh Kumar, NG Renganathan, None, A novel high power symmetric ZnO/carbon aerogel composite electrode for electrochemical supercapacitor Electrochimica Acta. ,vol. 52, pp. 1309- 1315 ,(2006) , 10.1016/J.ELECTACTA.2006.07.032
Md Nurul Islam, T.B. Ghosh, K.L. Chopra, H.N. Acharya, XPS and X-ray diffraction studies of aluminum-doped zinc oxide transparent conducting films Thin Solid Films. ,vol. 280, pp. 20- 25 ,(1996) , 10.1016/0040-6090(95)08239-5
J.M. Sieben, E. Morallón, D. Cazorla-Amorós, Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods Energy. ,vol. 58, pp. 519- 526 ,(2013) , 10.1016/J.ENERGY.2013.04.077