Crystallization and molecular dynamics of ethylene-vinyl acetate copolymer/butyl rubber blends
作者： Rui Zhang , Xianru He
DOI: 10.1039/C4RA10568K
关键词: Polymer chemistry 、 Morphology (linguistics) 、 Close relationship 、 Molecular dynamics 、 Ethylene-vinyl acetate 、 Crystal structure 、 Butyl rubber 、 Materials science 、 Copolymer 、 Chemical engineering 、 Crystallization
摘要: In this article, butyl rubber (IIR) was blended with ethylene-vinyl acetate copolymer (EVA) through a molten method. The crystal structure, morphology, crystallization and segmental dynamics were characterized. structure test indicated that IIR had no influence on the form of EVA. Furthermore, morphology showed blends changed from sea-island to co-continuous structure. Moreover, non-isothermal kinetics given by Mo’s model rate became fast as content EVA increased. addition, characterization illustrated suppressed molecular motions different degree. Longer units more influenced than shorter units. It also found both close relationship morphology.
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