Stabilization of battery electrodes using prussian blue analogue coatings

作者: Colin Deane Wessells , Robert Alan Huggins

DOI:

关键词: ElectrodeInorganic chemistryAnodeBattery (electricity)ElectrochemistryCathodePrussian blueLigandChemistryTransition metal

摘要: An electrochemical apparatus (e.g. a battery (cell)) including an aqueous electrolyte and one or two electrodes (e.g., anode and/or cathode), both of which includes Prussian Blue analogue (PBA) material the general chemical formula A x P[R(CN) 6-j L j ] z .nH 2 O, where: is cation; P metal R transition ligand that may be substituted in place CN − ligand; 0≦x≦2; 0≦z≦1; 0≦n≦5, PBA coating to decrease capacity loss.

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