Variable-Temperature Kinetic Analysis of a Three-Site Terminal Ligand Exchange in Nickel A-Frames by Quantitative31P{1H} EXSY NMR

作者: Jerald D. Heise , Daniel Raftery , Brian K. Breedlove , John Washington , Clifford P. Kubiak

DOI: 10.1021/OM980556J

关键词: CrystallographyNickelRedistribution (chemistry)Nuclear magnetic resonance spectroscopyKineticsKinetic analysisChemistry

摘要: Variable-temperature two-dimensional phase-sensitive 31P{1H} EXSY NMR spectroscopy was used to determine the kinetics and thermodynamics of terminal ligand redistribution in nickel A-frames Ni2...

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