The application of LIBS for the analysis of archaeological ceramic and metal artifacts

作者: Kristalia Melessanaki , Maripaz Mateo , Susan C Ferrence , Philip P Betancourt , Demetrios Anglos

DOI: 10.1016/S0169-4332(02)00459-2

关键词: Spectral dataCeramicGeologyMetal alloyAtomic emission spectrometryPotteryArchaeologyExcavationMetal analysisElemental composition

摘要: Abstract A bench-top laser-induced breakdown spectroscopy (LIBS) system has been used in the examination of pottery, jewelry and metal artifacts found archaeological excavations central eastern Crete, Greece. The objects date from Middle Late Minoan periods (ca. 20th–13th century b . c .) through Byzantine Venetian to Ottoman times 5th–19th a.d .). spectral data indicates qualitative often semi-quantitative elemental composition examined materials. In case colored glazed ceramics, identity pigments was established while analysis, type or alloy determined. analyses demonstrate potential LIBS technique for performing routine, rapid, on-site analysis objects, which leads quick characterization screening different types objects.

参考文章(17)
E. Ciliberto, G. Spoto, Modern analytical methods in art and archaeology Wiley. ,(2000)
Ian M. Bell, Robin J.H. Clark, Peter J. Gibbs, Raman spectroscopic library of natural and synthetic pigments (pre- ≈ 1850 AD) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 53, pp. 2159- 2179 ,(1997) , 10.1016/S1386-1425(97)00140-6
Demetrios Anglos, Stelios Couris, Costas Fotakis, Laser Diagnostics of Painted Artworks: Laser-Induced Breakdown Spectroscopy in Pigment Identification Applied Spectroscopy. ,vol. 51, pp. 1025- 1030 ,(1997) , 10.1366/0003702971941421
Lucia Burgio, Robin J.H Clark, Library of FT-Raman spectra of pigments, minerals, pigment media and varnishes, and supplement to existing library of Raman spectra of pigments with visible excitation. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 57, pp. 1491- 1521 ,(2001) , 10.1016/S1386-1425(00)00495-9
Yoonyeol Yoon, Taesam Kim, Myeongkwon Yang, Kilyong Lee, Gaeho Lee, Quantitative analysis of pottery glaze by laser induced breakdown spectroscopy Microchemical Journal. ,vol. 68, pp. 251- 256 ,(2001) , 10.1016/S0026-265X(00)00155-7
Michael Mantler, Manfred Schreiner, X‐ray fluorescence spectrometry in art and archaeology X-Ray Spectrometry. ,vol. 29, pp. 3- 17 ,(2000) , 10.1002/(SICI)1097-4539(200001/02)29:1<3::AID-XRS398>3.0.CO;2-O
H. G. M. Edwards, J. K. F. Tait, FT-Raman Spectroscopic Study of Decorated Stained Glass Applied Spectroscopy. ,vol. 52, pp. 679- 682 ,(1998) , 10.1366/0003702981944346
Lucia Burgio, Robin J. H. Clark, Theodosia Stratoudaki, Michael Doulgeridis, Demetrios Anglos, Pigment Identification in Painted Artworks: A Dual Analytical Approach Employing Laser-Induced Breakdown Spectroscopy and Raman Microscopy: Applied Spectroscopy. ,vol. 54, pp. 463- 469 ,(2000) , 10.1366/0003702001949861