作者: F Figueras , B Mencier , L De Mourgues , C Naccache , Y Trambouze
DOI: 10.1016/0021-9517(70)90253-8
关键词: Tetracyanoethylene 、 Dehydrogenation 、 Photochemistry 、 Metal 、 Redox 、 Platinum 、 Oxidizing agent 、 Cyclohexane 、 Chemistry 、 Inorganic chemistry 、 Catalysis
摘要: Abstract Platinum has been deposited on a series of silica-alumina supports with different alumina contents; the dispersion platinum is found to be constant. The catalytic activity for cyclohexane dehydrogenation increases when content decreases. tert-butanol dehydration and perylene cation formation decreases support. In contrast, number sites producing tetracyanoethylene anion increases. existence charge-transfer complex between metal oxidizing support could explain variations redox properties.