Rare Earth Element Recovery from Acidic Extracts of Florida Phosphate Mining Materials Using Chelating Polymer 1-Octadecene, Polymer with 2,5-Furandione, Sodium Salt
作者： Joseph P. Laurino , Jack Mustacato , Zachary J. Huba
DOI: 10.3390/MIN9080477
关键词: Phosphogypsum 、 Nuclear chemistry 、 Praseodymium 、 Rare-earth element 、 Scandium 、 Phosphate 、 Chemistry 、 Tailings 、 Phosphorite 、 Extraction (chemistry)
摘要: To meet the growing global demand for rare earth elements (REEs), nontraditional mining sources of these metals are being investigated. Phosphate ore and phosphate wastes have been identified as possible alternative to REEs. In this study, REEs were extracted from Florida materials using mineral organic acids. The then recovered at high efficiencies a chelating polymer, 1-octadecene, polymer with 2,5-furandione, sodium salt. At pH 1.5, chelation effectively bound nearly 100% solids. Overall extraction recovery yields between 80% gadolinium 8% praseodymium amine tailings, 70% terbium 7% phosphogypsum, 56% scandium 15% rock, 77% samarium 31% waste clay. These results suggest that efficiently recovers acidic extracts products.
mdpi.com
sci-hub.se 参考文章(25)
Keith W. Goyne, Susan L. Brantley, Jon Chorover, Rare earth element release from phosphate minerals in the presence of organic acids Chemical Geology. ,vol. 278, pp. 1- 14 ,(2010) , 10.1016/J.CHEMGEO.2010.03.011
Patrick Zhang, Comprehensive Recovery and Sustainable Development of Phosphate Resources Procedia Engineering. ,vol. 83, pp. 37- 51 ,(2014) , 10.1016/J.PROENG.2014.09.010
A.M. Feather, J.S. Preston, P.M. Cole, W.M. Craig, The recovery of rare earth oxides from a phosphoric acid by-product. Part 1: Leaching of rare earth values and recovery of a mixed rare earth oxide by solvent extraction Hydrometallurgy. ,vol. 41, pp. 1- 19 ,(1996) , 10.1016/0304-386X(95)00051-H
S. Al-Thyabat, P. Zhang, REE extraction from phosphoric acid, phosphoric acid sludge, and phosphogypsum Mineral Processing and Extractive Metallurgy. ,vol. 124, pp. 143- 150 ,(2015) , 10.1179/1743285515Y.0000000002
P. Zhang, M. Bogan, Recovery of phosphate from Florida beneficiation slimes I. Re-identifying the problem Minerals Engineering. ,vol. 8, pp. 523- 534 ,(1995) , 10.1016/0892-6875(95)00014-H
Poul Emsbo, Patrick I. McLaughlin, George N. Breit, Edward A. du Bray, Alan E. Koenig, Rare earth elements in sedimentary phosphate deposits: Solution to the global REE crisis? Gondwana Research. ,vol. 27, pp. 776- 785 ,(2015) , 10.1016/J.GR.2014.10.008
Serpil Edebali, Erol Pehlivan, Evaluation of Cr(III) by ion-exchange resins from aqueous solution: equilibrium, thermodynamics and kinetics Desalination and Water Treatment. ,vol. 52, pp. 7143- 7153 ,(2014) , 10.1080/19443994.2013.821631
Liangshi Wang, Zhiqi Long, Xiaowei Huang, Ying Yu, Dali Cui, Guocheng Zhang, Recovery of rare earths from wet-process phosphoric acid Hydrometallurgy. ,vol. 101, pp. 41- 47 ,(2010) , 10.1016/J.HYDROMET.2009.11.017
Alexander Mishelevich, Alexander Apelblat, Solubilities of magnesium-l-ascorbate, calcium-l-ascorbate, magnesium-l-glutamate, magnesium-d-gluconate, calcium-d-gluconate, calcium-d-heptagluconate, l-aspartic acid, and 3-nitrobenzoic acid in water The Journal of Chemical Thermodynamics. ,vol. 40, pp. 897- 900 ,(2008) , 10.1016/J.JCT.2007.12.006
Joseph P. Laurino, Removal of Lead (II) Ions by Poly(2‐octadecyl butanedioic acid): Isothermal and Kinetic Studies Journal of Macromolecular Science, Part A. ,vol. 45, pp. 612- 619 ,(2008) , 10.1080/10601320802168736