Catalytic Decomposition of Hydrogen Peroxide by Fe(III) in Homogeneous Aqueous Solution: Mechanism and Kinetic Modeling

作者： Joseph De Laat , HervÉ Gallard

关键词: Chemical decomposition 、 Reaction mechanism 、 Hydrogen peroxide 、 Decomposition 、 Physical chemistry 、 Inorganic chemistry 、 Reaction rate constant 、 Chemistry 、 Kinetics 、 Aqueous solution 、 Catalysis

摘要: … 1 M; 50 μM ≤ [Fe(III)] 0 ≤ 1 mM; 1 ≤ [H 2 O 2 ] 0 /[Fe(III)] 0 ≤ … rate of decomposition of hydrogen peroxide by Fe(III) could … of Fe(III)−hydroperoxy complexes (Fe III (HO 2 ) 2+ and Fe III (…