An electrochemical method to rapidly assess the environmental risk of silver release from nanowire transparent conductive films

作者: Brenda Omaña-Sanz , Djadidi Toybou , Ludovic Lesven , Valerie Gaucher , Alexandre Fadel

DOI: 10.1016/J.IMPACT.2020.100217

关键词: MicroelectrodeCorrosionPolymerNanomaterialsElectrochemistryCoatingNanowireNanotechnologyBiosensorMaterials science

摘要: Abstract Silver nanowires (AgNW) are new nanomaterials designed to be incorporated into transparent conductive films in electronics, microelectrodes, heated surfaces and others. Although these films, the AgNW generally protected by a coating material, risk for release of silver at all stages nanoproduct life cycle does exist due corrodibility metal. Since ionic nanoparticulate Ag represent toxicological large number living cells, there is need quantifying potential from product components. We developed an electrochemical method evaluate possible corrosion activity (TCFs) concomitant Ag+ release. A polysiloxane polymer was used as protective TCFs. consistent correlation observed between degree coatings' characteristics, particular thicknesses. major advantage approach, compared classical aging studies, short experimentation time: 20 min sufficient diagnostic result. The accelerated test. It environmentally sound methodology with use very low electric power no harmful reagents. particularly attractive application could field environmental assessment metals portable electronics biosensors.

参考文章(50)
Seyul Kim, So Yeon Kim, Moon Hyun Chung, Jeonghun Kim, Jung Hyun Kim, A one-step roll-to-roll process of stable AgNW/PEDOT:PSS solution using imidazole as a mild base for highly conductive and transparent films: optimizations and mechanisms Journal of Materials Chemistry C. ,vol. 3, pp. 5859- 5868 ,(2015) , 10.1039/C5TC00801H
Céline Mayousse, Caroline Celle, Alexandra Fraczkiewicz, Jean-Pierre Simonato, Stability of silver nanowire based electrodes under environmental and electrical stresses Nanoscale. ,vol. 7, pp. 2107- 2115 ,(2015) , 10.1039/C4NR06783E
S. Chen, L. Song, Z. Tao, X. Shao, Y. Huang, Q. Cui, X. Guo, Neutral-pH PEDOT:PSS as over-coating layer for stable silver nanowire flexible transparent conductive films Organic Electronics. ,vol. 15, pp. 3654- 3659 ,(2014) , 10.1016/J.ORGEL.2014.09.047
Feng Xu, Yong Zhu, Highly Conductive and Stretchable Silver Nanowire Conductors Advanced Materials. ,vol. 24, pp. 5117- 5122 ,(2012) , 10.1002/ADMA.201201886
Ivan Moreno, Nuria Navascues, Manuel Arruebo, Silvia Irusta, Jesus Santamaria, Facile preparation of transparent and conductive polymer films based on silver nanowire/polycarbonate nanocomposites. Nanotechnology. ,vol. 24, pp. 275603- 275603 ,(2013) , 10.1088/0957-4484/24/27/275603
Julia Farkas, Paul Christian, Julián Alberto Gallego Urrea, Norbert Roos, Martin Hassellöv, Knut Erik Tollefsen, Kevin V. Thomas, Effects of silver and gold nanoparticles on rainbow trout (Oncorhynchus mykiss) hepatocytes. Aquatic Toxicology. ,vol. 96, pp. 44- 52 ,(2010) , 10.1016/J.AQUATOX.2009.09.016
V. Brusic, G. S. Frankel, J. Roldan, R. Saraf, Corrosion and Protection of a Conductive Silver Paste Journal of The Electrochemical Society. ,vol. 142, pp. 2591- 2594 ,(1995) , 10.1149/1.2050058
P Davies, Toxicity of silver to rainbow trout (Salmo gairdneri) Water Research. ,vol. 12, pp. 113- 117 ,(1978) , 10.1016/0043-1354(78)90014-3
Jose Luis Elechiguerra, Leticia Larios-Lopez, Cui Liu, Domingo Garcia-Gutierrez, Alejandra Camacho-Bragado, Miguel Jose Yacaman, None, Corrosion at the Nanoscale: The Case of Silver Nanowires and Nanoparticles Chemistry of Materials. ,vol. 17, pp. 6042- 6052 ,(2005) , 10.1021/CM051532N
Marie-Noële Croteau, Superb K. Misra, Samuel N. Luoma, Eugenia Valsami-Jones, Silver bioaccumulation dynamics in a freshwater invertebrate after aqueous and dietary exposures to nanosized and ionic Ag Environmental Science & Technology. ,vol. 45, pp. 6600- 6607 ,(2011) , 10.1021/ES200880C