Experimental and thermodynamic constraints on mineral equilibrium inpantelleritic magmas

作者: Pierangelo Romano , Bruno Scaillet , John C. White , Joan Andújar , Ida Di Carlo

DOI: 10.1016/J.LITHOS.2020.105793

关键词: FayalitePeralkaline rockGeochemistryGeologyLiquidusMineralOlivineAnorthoclaseAenigmatiteAmphibole

摘要: Abstract Crystallization experiments on two pantellerites from Pantelleria, Italy, provide new evidence for the relationships between mineral phases in pantelleritic rocks as well influence of temperature and redox conditions assemblages. Experiments were performed at 1 kbar with ranging 750–900°C, fluid saturation XH2O (=H2O/H2O+CO2) 0 1. Redox fixed at, or slightly below, FMQ buffer. Results show that 900 °C magmas are above liquidus regardless their water content; we also observed a decrease (800°C) increasingly reducing conditions. Mineral assemblages natural have been successfully reproduced, particularly relationship fayalite aenigmatite, which appear to be strongly controlled by melt peralkalinity, This is first time fayalitic olivine synthetized experimental studies pantellerites, was found stable only temperatures ≥750°C while amphibole can high 800°C fF2. Experimental results compared composition obtained equilibrium, geothermometry, oxygen barometry lava tuffs Pantelleria (Italy), Eburru (Kenya) Menengai (Kenya). Petrological characteristics similar different locations worldwide, typical anorthoclase sodian clinopyroxene variable fayalite, Fe-Ti oxides amphibole.

参考文章(74)
Francis Albarède, Introduction to Geochemical Modeling ,(1995)
John R. Holloway, Nicholas F. Davis, C. Wayne Burnham, Thermodynamic properties of water to 1,000 C and 10,000 bars ,(1969)
R. MacDonald, Nomenclature and petrochemistry of the peralkaline oversaturated extrusive rocks Bulletin Volcanologique. ,vol. 38, pp. 498- 516 ,(1974) , 10.1007/BF02596896
Gail A. Mahood, Pyroclastic rocks and calderas associated with strongly peralkaline magmatism Journal of Geophysical Research. ,vol. 89, pp. 8540- 8552 ,(1984) , 10.1029/JB089IB10P08540
A. Gioncada, P. Landi, The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy) Journal of Volcanology and Geothermal Research. ,vol. 189, pp. 191- 201 ,(2010) , 10.1016/J.JVOLGEORES.2009.11.006
Ian S. E. Carmichael, The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates Contributions to Mineralogy and Petrology. ,vol. 14, pp. 36- 64 ,(1966) , 10.1007/BF00370985