Biotransformation of (+)- and (−)-camphorquinones to camphanediols by Glomerella cingulata

作者: Mitsuo Miyazawa , Masahiro Nobata , Mitsuro Hyakumachi , Hiromu Kameoka

DOI: 10.1016/S0031-9422(96)00516-X

关键词: BiologyStereoselectivityBiotransformationQuinoneStereochemistryDiolGlomerella cingulata

摘要: Abstract The reduction of (+)-camphorquinone by the plant pathogen Glomerella cingulata produced (+)-2- exo -3- -2,3-diol with high stereoselectivity, whereas (−)-camphorquinone yielded endo stereo- and enantioselectivity.

参考文章(3)
Mitsuo Miyazawa, Masahiro Nobata, Mitsuro Hyakumachi, Hiromu Kameoka, Biotransformation of (+)- and (−)-camphorquinones by fungi Phytochemistry. ,vol. 39, pp. 569- 573 ,(1995) , 10.1016/0031-9422(94)00978-3
J. S. Robertson, E. Solomon, Metabolism of camphanediols Biochemical Journal. ,vol. 121, pp. 503- 509 ,(1971) , 10.1042/BJ1210503
Tuula Partanen, Pentti J. Mälkönen, Pirjo Vainiotalo, Jouko Vepsäläinen, Differentiation of isomeric camphane-2,3-diols by NMR spectroscopy and chemical ionization mass spectrometry Journal of The Chemical Society-perkin Transactions 1. pp. 777- 782 ,(1990) , 10.1039/P29900000777