Effects of annulation on the mass spectral behaviour of bicyclo[4.3.0]-3-nonene derivatives: Alkoxy esters
作者： F. Tureček , V. Hanuš
关键词: Nonene 、 Bicyclic molecule 、 Alkoxy group 、 Annulation 、 Ether 、 Chemistry 、 Fragmentation (mass spectrometry) 、 Alcohol 、 Benzene 、 Organic chemistry 、 Instrumentation (computer programming) 、 Molecular medicine 、 Biochemistry
摘要: Fragmentation of ethyl(18-alkoxybicyclo[4.3.0]-3-nonene-7-carboxylates) was found to depend on the annulation rings. Following ionization, cis-annulated isomers lose alcohol and benzene, while trans-isomers fragment by other reaction paths. The regiospecificity elimination from both ester ether groups determined using deuterium-labelled analogues. A mechanism is discussed which rationalizes differences observed in spectra isomers.
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