Novel Sandwich Coordination Polymers Composed of Cobalt(II), 1,2,4,5-Benzenetetracarboxylato Ligands, and Homopiperazonium Cations
作者： Deping Cheng , Masood A. Khan , Robert P. Houser
DOI: 10.1021/CG025547Z
关键词: Triclinic crystal system 、 Cobalt 、 Crystallography 、 Molecule 、 Aqueous solution 、 Stereochemistry 、 Hydrate 、 Carboxylate 、 Crystal structure 、 Lamellar structure 、 Chemistry
摘要: Two novel cobalt(II) coordination polymers, (H 4 hpz)[Co 3 (BTEC) 2 O) 12 ].11H O (1) and hpz)[Co(BTEC)(H ].3H (2) hpz = homopiperazonium; BTEC 1,2,4,5-benzenetetracarboxylate), have been synthesized under aqueous conditions at room temperature structurally characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in the triclinic space group P1ο1 with a 9.823(4) A, b 11.587(4) c 20.385(7) α 95.10(2)°, β 92.423(19)°, γ 98.90(2)°, Z 2. also P1 9.7755(17) 11.208(3) 11.224(2) 60.304(12)°, 73.687(12)°, 84.311(14)°, Both compounds layered structures. In case of 1, homopiperazonium cations 1D anionic chains [Co(BTEC)(H ] 2- n are sandwiched between 2D sheets [Co (BTEC)(H 8 . 2, alone
acs.org
sci-hub.se 参考文章(17)
Brian Moulton, Michael J. Zaworotko, From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids. Chemical Reviews. ,vol. 101, pp. 1629- 1658 ,(2001) , 10.1021/CR9900432
Fernande D. Rochon, Gassan Massarweh, Study of the aqueous reactions of metallic ions with benzenetetracarboxylate ions Inorganica Chimica Acta. ,vol. 304, pp. 190- 198 ,(2000) , 10.1016/S0020-1693(00)00086-4
F. A. Cotton, C. Lin, C. A. Murillo, The use of dimetal building blocks in convergent syntheses of large arrays Proceedings of the National Academy of Sciences of the United States of America. ,vol. 99, pp. 4810- 4813 ,(2002) , 10.1073/PNAS.012567599
Lee, Kim, Duk-Young Jung, A coordination polymer of cobalt(II)-glutarate: two-dimensional interlocking structure by dicarboxylate ligands with two different conformations. Inorganic Chemistry. ,vol. 41, pp. 501- 506 ,(2002) , 10.1021/IC010861O
Ramaswamy Murugavel, Divya Krishnamurthy, Malaichamy Sathiyendiran, Anionic metal–organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4}·{C4H12N2}·4H2O]n (M = Co, Ni, and Zn; BTEC = 1,2,4,5-benzenetetracarboxylate) Journal of The Chemical Society-dalton Transactions. pp. 34- 39 ,(2002) , 10.1039/B105687P
Samuel M-F. Lo, Stephen S-Y. Chui, Lai-Yung Shek, Zhenyang Lin, Xi Xiang Zhang, Ge-hei Wen, Ian D. Williams, Solvothermal Synthesis of a Stable Coordination Polymer with Copper-I−Copper-II Dimer Units: [Cu4{1,4-C6H4(COO)2}3(4,4‘-bipy)2]n Journal of the American Chemical Society. ,vol. 122, pp. 6293- 6294 ,(2000) , 10.1021/JA000416C
Ch. Robl, Komplexe mit aromatischen Carbonsäuren. I: Darstellung und Struktur von Zinkpyromellitat-Heptahydrat Zeitschrift für anorganische und allgemeine Chemie. ,vol. 554, pp. 79- 86 ,(1987) , 10.1002/ZAAC.19875541109
Deping Cheng, Changjian Feng, Maolin Hu, Yueqing Zheng, Duanjun Xu, Yuanzhi Xu, SYNTHESIS AND CRYSTAL STRUCTURE OF A POLYMERIC 1,2,4,5-BENZENETETRACARBOXYLATO COMPLEX OF Cu(II) WITH IMIDAZOLE, Cu2(C10H2O8)(C3H4N2)6(H2O)4 · 4H2O Journal of Coordination Chemistry. ,vol. 52, pp. 245- 251 ,(2001) , 10.1080/00958970108022590
Maolin Hu, Deping Cheng, Jiageng Liu, Duanjun Xu, STRUCTURE OF A POLYMERIC BENZENETETRACARBOXYLATO COMPLEX OF Mn(II) WITH IMIDAZOLE Journal of Coordination Chemistry. ,vol. 53, pp. 7- 13 ,(2001) , 10.1080/00958970108022596
Hitoshi Kumagai, Cameron J. Kepert, Mohamedally Kurmoo, Construction of hydrogen-bonded and coordination-bonded networks of cobalt(II) with pyromellitate: synthesis, structures, and magnetic properties. Inorganic Chemistry. ,vol. 41, pp. 3410- 3422 ,(2002) , 10.1021/IC020065Y