Decontamination of water using adsorption and photocatalysis

作者: John C. Crittenden , Rominder P.S. Suri , David L. Perram , David W. Hand

DOI: 10.1016/S0043-1354(96)00258-8

关键词: ChemistryHydrocarbonBenzeneHuman decontaminationBTEXPhotocatalysisAdsorptionWater pollutionEnvironmental chemistryTolueneEcological modellingWaste Management and DisposalPollutionWater Science and Technology

摘要: Abstract A treatment strategy employing adsorption and solar assisted photocatalytic processes was field tested at Tyndall Air Force Base (Florida) for removal destruction of organic contaminants in groundwater. The adsorbents were impregnated with photoactive catalysts used packed beds to remove pollutants from water 18 h per day. spent regenerated 6 day the presence sunlight while passing hot (90°C) counter current flow direction during process. organics that not destroyed regeneration by catalyst-impregnated adsorbent using a fixed bed reactor. process examined 10 cycles contaminated BTEX (benzene, toluene, ethyl benzene, o-xylene, m-xylene, p-xylene) compounds. efficiency (ratio amount removed adsorbed) regenerate each cycle. laboratory study also conducted under controlled conditions tetrachloroethylene as model compound examine 8 regeneration.

参考文章(29)
Ezio Pelizzetti, Nick Serpone, Enrico Borgarello, Michael Graetzel, Massimo Barbeni, Edmondo Pramauro, Photodegradation of 4-chlorophenol catalyzed by titanium dioxide particles Nouveau journal de chimie. ,vol. 8, pp. 547- 550 ,(1984)
Radisav D. Vidic, Makram T. Suidan, George A. Sorial, Richard C. Brenner, Molecular oxygen and the adsorption of phenols-effect of functional groups Water Environment Research. ,vol. 65, pp. 156- 161 ,(1993) , 10.2175/WER.65.2.8
Keith O Wilbourn, Fu-Ren F Fan, Allen J Bard, Wendell W Dunn, Ikuichiro Izumi, The Heterogeneous Photocatalytic Oxidation of Hydrocarbons on Platinized TiO2 Powders. ,(1980)
William H. Glaze, John F. Kenneke, John L. Ferry, Chlorinated byproducts from the titanium oxide-mediated photodegradation of trichloroethylene and tetrachloroethylene in water Environmental Science & Technology. ,vol. 27, pp. 177- 184 ,(1993) , 10.1021/ES00038A021
David F. Ollis, Ezio Pelizzetti, Nick Serpone, Photocatalyzed destruction of water contaminants Environmental Science & Technology. ,vol. 25, pp. 1522- 1529 ,(1991) , 10.1021/ES00021A001
Sawang Notthakun, John C. Crittenden, David W. Hand, David L. Perram, Michael E. Mullins, Regeneration of Adsorbents Using Heterogeneous Advanced Oxidation Journal of Environmental Engineering. ,vol. 119, pp. 695- 714 ,(1993) , 10.1061/(ASCE)0733-9372(1993)119:4(695)
Nick Serpone, Enrico Borgarello, Ron Harris, Paul Cahill, Marco Borgarello, Ezio Pelizzetti, Photocatalysis over TiO2 supported on a glass substrate Solar Energy Materials. ,vol. 14, pp. 121- 127 ,(1986) , 10.1016/0165-1633(86)90070-5
Ralph W. Matthews, Photooxidation of organic impurities in water using thin films of titanium dioxide The Journal of Physical Chemistry. ,vol. 91, pp. 3328- 3333 ,(1987) , 10.1021/J100296A044