The solvent effect on the Diels–Alder reaction in ionic liquids: multiparameter linear solvation energy relationships and theoretical analysis
作者： Cinzia Chiappe , Marco Malvaldi , Christian Silvio Pomelli
DOI: 10.1039/C0GC00074D
关键词: Solvent 、 Computational chemistry 、 Diels–Alder reaction 、 Solvation 、 Ionic bonding 、 Solvent effects 、 Chemistry 、 Ionic liquid 、 Reaction rate 、 Organic chemistry 、 Reaction mechanism
摘要: This review illustrates how ionic liquid properties can affect Diels–Alder reactions. The mechanisms by which solvents enhance the rate and selectivity of reaction are discussed on basis correlation studies using empirical parameters theoretical calculations.
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