Mesoscopic architectures of Co(OH)2 spheres with an extended array of microporous threads as pseudocapacitor electrode materials

作者: Anoop Somanathan Pillai , Ranjusha Rajagopalan , A Amruthalakshmi , Jickson Joseph , Amrutha Ajay

DOI: 10.1016/J.COLSURFA.2015.01.068

关键词: ElectrolyteSupercapacitorMaterials scienceHydroxideCobalt hydroxideChemical engineeringLithium hydroxidePseudocapacitorNanotechnologyPotassium hydroxideNano-

摘要: Abstract The present study demonstrates a low temperature hydrothermal route for the synthesis of α-cobalt hydroxide comprising randomly arrayed nano strands in three dimensional plane. These micro/nano hybrid structures were used as building blocks processing high surface area supercapacitor electrodes. Surface these was measured to be ∼100 m2 g−1. influence morphology different electrolytes namely lithium hydroxide, sodium and potassium analyzed. on capacitance internal resistance also determined explained basis redox reactions electrolytes. Capacitance values 1024 F g−1 attained when employed thin film electrodes with life extending more than 5000 cycles. Inductively coupled plasma-atomic emission spectroscopy determine electrode dissolution given electrolyte observations co-related cycling stability. Low self-discharge, rate capability along cost makes them promising systems applications.

参考文章(34)
Amruthalakshmi Vijayakumar, Ranjusha Rajagopalan, Anoop S Sushamakumariamma, Jickson Joseph, Amrutha Ajay, Shantikumar V Nair, MS Deepak Krishna, Avinash Balakrishnan, None, Synergetic influence of ex-situ camphoric carbon nano-grafting on lithium titanates for lithium ion capacitors Journal of Energy Chemistry. ,vol. 24, pp. 337- 345 ,(2015) , 10.1016/S2095-4956(15)60320-5
Jickson Joseph, Ranjusha Rajagopalan, SS Anoop, V Amruthalakshmi, Amrutha Ajay, Shantikumar V Nair, Avinash Balakrishnan, None, Shape tailored Ni3(NO3)2(OH)4 nano-flakes simulating 3-D bouquet-like structures for supercapacitors: exploring the effect of electrolytes on stability and performance RSC Advances. ,vol. 4, pp. 39378- 39385 ,(2014) , 10.1039/C4RA05054A
Zhong-Ai Hu, Yu-Long Xie, Yao-Xian Wang, Li-Jing Xie, Guo-Rui Fu, Xiao-Qing Jin, Zi-Yu Zhang, Yu-Ying Yang, Hong-Ying Wu, Synthesis of α-Cobalt Hydroxides with Different Intercalated Anions and Effects of Intercalated Anions on Their Morphology, Basal Plane Spacing, and Capacitive Property Journal of Physical Chemistry C. ,vol. 113, pp. 12502- 12508 ,(2009) , 10.1021/JP8106809
A.D. Jagadale, V.S. Kumbhar, D.S. Dhawale, C.D. Lokhande, Performance evaluation of symmetric supercapacitor based on cobalt hydroxide [Co(OH)2] thin film electrodes Electrochimica Acta. ,vol. 98, pp. 32- 38 ,(2013) , 10.1016/J.ELECTACTA.2013.02.094
Xi Tan, Hongyi Gao, Mu Yang, Yi Luan, Wenjun Dong, Zhaokui Jin, Jie Yu, Yue Qi, Yanhui Feng, Ge Wang, Synthesize of hierarchical sisal-like cobalt hydroxide and its electrochemical applications Journal of Alloys and Compounds. ,vol. 608, pp. 278- 282 ,(2014) , 10.1016/J.JALLCOM.2014.04.042
Yongfu Tang, Yanyan Liu, Shengxue Yu, Shichun Mu, Shaohua Xiao, Yufeng Zhao, Faming Gao, Morphology controlled synthesis of monodisperse cobalt hydroxide for supercapacitor with high performance and long cycle life Journal of Power Sources. ,vol. 256, pp. 160- 169 ,(2014) , 10.1016/J.JPOWSOUR.2014.01.064
P Anjali, R Vani, TS Sonia, A Sreekumaran Nair, Seeram Ramakrishna, R Ranjusha, KRV Subramanian, N Sivakumar, C Gopi Mohan, Shantikumar V Nair, Avinash Balakrishnan, None, Cerium Doped NiO Nanoparticles: A Novel Electrode Material for High Performance Pseudocapacitor Applications Science of Advanced Materials. ,vol. 6, pp. 94- 101 ,(2014) , 10.1166/SAM.2014.1684
Yongzheng Shao, Jing Sun, Lian Gao, Hydrothermal Synthesis of Hierarchical Nanocolumns of Cobalt Hydroxide and Cobalt Oxide Journal of Physical Chemistry C. ,vol. 113, pp. 6566- 6572 ,(2009) , 10.1021/JP9005718
Rutao Wang, Xingbin Yan, Junwei Lang, Zongmin Zheng, Peng Zhang, A hybrid supercapacitor based on flower-like Co(OH)2 and urchin-like VN electrode materials Journal of Materials Chemistry. ,vol. 2, pp. 12724- 12732 ,(2014) , 10.1039/C4TA01296H
Mathieu Toupin, Thierry Brousse, Daniel Bélanger, Charge Storage Mechanism of MnO2 Electrode Used in Aqueous Electrochemical Capacitor Chemistry of Materials. ,vol. 16, pp. 3184- 3190 ,(2004) , 10.1021/CM049649J