作者: Anoop Somanathan Pillai , Ranjusha Rajagopalan , A Amruthalakshmi , Jickson Joseph , Amrutha Ajay
DOI: 10.1016/J.COLSURFA.2015.01.068
关键词: Electrolyte 、 Supercapacitor 、 Materials science 、 Hydroxide 、 Cobalt hydroxide 、 Chemical engineering 、 Lithium hydroxide 、 Pseudocapacitor 、 Nanotechnology 、 Potassium hydroxide 、 Nano-
摘要: Abstract The present study demonstrates a low temperature hydrothermal route for the synthesis of α-cobalt hydroxide comprising randomly arrayed nano strands in three dimensional plane. These micro/nano hybrid structures were used as building blocks processing high surface area supercapacitor electrodes. Surface these was measured to be ∼100 m2 g−1. influence morphology different electrolytes namely lithium hydroxide, sodium and potassium analyzed. on capacitance internal resistance also determined explained basis redox reactions electrolytes. Capacitance values 1024 F g−1 attained when employed thin film electrodes with life extending more than 5000 cycles. Inductively coupled plasma-atomic emission spectroscopy determine electrode dissolution given electrolyte observations co-related cycling stability. Low self-discharge, rate capability along cost makes them promising systems applications.