Mixed Oxidation States and Averaged Electronic Environments in Iron Compounds
作者： W. M. Reiff
DOI: 10.1007/978-1-4684-3162-9_6
关键词: Covalent bond 、 Electron exchange 、 Materials science 、 Mössbauer spectroscopy 、 Bond length 、 Physical chemistry 、 Prussian blue 、 Valence (chemistry) 、 Coordination complex 、 Oxidation state
摘要: A survey of the iron-57 Mossbauer spectroscopy a variety mixed valence compounds is presented. The systems discussed are grouped into two broad categories: highly covalent iron-sulfur and coordination exhibiting range covalency. Correlations intermediate values chemical isomer shift as well average ironligand bond distance with electron exchange oxidation state averaging considered.
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