Boron Doping of SWCNTs as a Way to Enhance the Thermoelectric Properties of Melt-Mixed Polypropylene/SWCNT Composites
作者： Beate Krause , Viktor Bezugly , Vyacheslav Khavrus , Liu Ye , Gianaurelio Cuniberti
DOI: 10.3390/EN13020394
关键词: Percolation threshold 、 Nanocomposite 、 Electrical resistivity and conductivity 、 Composite material 、 Thermoelectric effect 、 Carbon nanotube 、 Materials science 、 Crystallinity 、 Crystallization 、 Seebeck coefficient
摘要: Composites based on the matrix polymer polypropylene (PP) filled with single-walled carbon nanotubes (SWCNTs) and boron-doped SWCNTs (B-SWCNTs) were prepared by melt-mixing to analyze influence of boron doping thermoelectric properties these nanocomposites. It was found that besides a significantly higher Seebeck coefficient B-SWCNT films powder packages, values for incorporated in PP than those SWCNTs. Due electrical conductivity coefficients B-SWCNTs, power factor (PF) figure merit (ZT) also PP/B-SWCNT composites. The highest value achieved this study 59.7 µV/K 0.5 wt% compared 47.9 at same filling level. PF 0.78 µW/(m·K2) 7.5 B-SWCNT. SWCNT macro- microdispersions be similar both composite types, as very low percolation threshold between 0.075 0.1 SWCNT. At loadings 2.0 wt%, B-SWCNT-based composites have one order magnitude crystallization behavior is more strongly influenced B-SWCNTs since their temperatures comparable degree crystallinity. Boron therefore suitable way improve
mdpi.com
sci-hub.se 参考文章(35)
David Michael Rowe, CRC Handbook of Thermoelectrics CRC Press. ,(1995) , 10.1201/9781420049718
Yu-Chen Sun, Daryl Terakita, Alex C Tseng, Hani E Naguib, Study on the thermoelectric properties of PVDF/MWCNT and PVDF/GNP composite foam Smart Materials and Structures. ,vol. 24, pp. 085034- ,(2015) , 10.1088/0964-1726/24/8/085034
Z. Antar, J.F. Feller, H. Noël, P. Glouannec, K. Elleuch, Thermoelectric behaviour of melt processed carbon nanotube/graphite/poly(lactic acid) conductive biopolymer nanocomposites (CPC) Materials Letters. ,vol. 67, pp. 210- 214 ,(2012) , 10.1016/J.MATLET.2011.09.060
Yeontack Ryu, Dallas Freeman, Choongho Yu, High electrical conductivity and n-type thermopower from double-/single-wall carbon nanotubes by manipulating charge interactions between nanotubes and organic/inorganic nanomaterials Carbon. ,vol. 49, pp. 4745- 4751 ,(2011) , 10.1016/J.CARBON.2011.06.082
Illayathambi Kunadian, Rodney Andrews, M. Pinar Mengüç, Dali Qian, Thermoelectric power generation using doped MWCNTs Carbon. ,vol. 47, pp. 589- 601 ,(2009) , 10.1016/J.CARBON.2008.10.043
Mingxing Piao, Mina Rastegar Alam, Gyutae Kim, Urszula Dettlaff-Weglikowska, Siegmar Roth, Effect of chemical treatment on the thermoelectric properties of single walled carbon nanotube networks physica status solidi (b). ,vol. 249, pp. 2353- 2356 ,(2012) , 10.1002/PSSB.201200101
Philip G Collins, Keith Bradley, Masa Ishigami, d A Zettl, Extreme oxygen sensitivity of electronic properties of carbon nanotubes Science. ,vol. 287, pp. 1801- 1804 ,(2000) , 10.1126/SCIENCE.287.5459.1801
Lazaros Tzounis, Titus Gärtner, Marco Liebscher, Petra Pötschke, Manfred Stamm, Brigitte Voit, Gert Heinrich, Influence of a cyclic butylene terephthalate oligomer on the processability and thermoelectric properties of polycarbonate/MWCNT nanocomposites Polymer. ,vol. 55, pp. 5381- 5388 ,(2014) , 10.1016/J.POLYMER.2014.08.048
Marco Liebscher, Titus Gärtner, Lazaros Tzounis, Matej Mičušík, Petra Pötschke, Manfred Stamm, Gert Heinrich, Brigitte Voit, Influence of the MWCNT surface functionalization on the thermoelectric properties of melt-mixed polycarbonate composites Composites Science and Technology. ,vol. 101, pp. 133- 138 ,(2014) , 10.1016/J.COMPSCITECH.2014.07.009
Olga Caballero-Calero, Marisol Martín-González, Thermoelectric nanowires: A brief prospective Scripta Materialia. ,vol. 111, pp. 54- 57 ,(2016) , 10.1016/J.SCRIPTAMAT.2015.04.020