Electronic (Absorption) Spectra of 3d Transition Metal Complexes

摘要: Since electronic excited states are sensitive to the local fluid environment, dopant transitions an appropriate probe study structure of near critical point fluids (i.e., perturbers). In comparison valence states, Rydberg more their environment [1]. However, high-n usually too perturber density fluctuations, which makes these individual impossible investigate. (Nevertheless, under assumption that state energies behave similarly ionization threshold dopant, behavior in supercritical can be probed indirectly by studying energy quasi-free electron, through photoinjection [2–11] and field [12–19].) Low-n on other hand, excellent spectroscopic probes investigate state/fluid interactions.