Conformal Surface Coatings to Enable High Volume Expansion Li‐Ion Anode Materials

作者: Leah A. Riley , Andrew S. Cavanagh , Steven M. George , Yoon Seok Jung , Yanfa Yan

DOI: 10.1002/CPHC.201000158

关键词: NanoparticleAnodeChemical engineeringCoatingMineralogyChemistryAtomic layer depositionElectrodeDielectric spectroscopyLithium batterySurface coating

摘要: An alumina surface coating is demonstrated to improve electrochemical performance of MoO3 nanoparticles as high capacity/high‐volume expansion anodes for Li‐ion batteries. Thin, conformal surface coatings were grown using atomic layer deposition (ALD) that relies on self‐limiting surface reactions. ALD coatings were tested on both individual nanoparticles and prefabricated electrodes containing conductive additive and binder. The coated and non‐coated materials were characterized using transmission electron microscopy, energy …

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