PECVD-ONO: A New Deposited Firing Stable Rear Surface Passivation Layer System for Crystalline Silicon Solar Cells

作者: M. Hofmann , S. Kambor , C. Schmidt , D. Grambole , J. Rentsch

DOI: 10.1155/2008/485467

关键词: Quantum dot solar cellCrystalline siliconPolymer solar cellElectronic engineeringPassivationPlasma-enhanced chemical vapor depositionQuantum efficiencySolar cellForming gasOptoelectronicsMaterials science

摘要: A novel plasma-enhanced chemical vapour deposited (PECVD) stack layer system consisting of a-:H, and a-:H is presented for silicon solar cell rear side passivation. Surface recombination velocities below 60 cm/s (after firing) 30 forming gas anneal) were achieved. Solar precursors without front metallisation showed implied open-circuit voltages values extracted from quasi-steady-state photoconductance (QSSPC) measurements above 680 mV. Fully finished cells with up to 20.0% energy conversion efficiency are presented. fit the cell's internal quantum using software tool PC1D a comparison full-area aluminium-back surface field (Al-BSF) thermal shown. PECVD-ONO was found be clearly superior Al-BSF. separation at metallised passivated area equations Fischer Kray. Nuclear reaction analysis (NRA) has been used evaluate hydrogen depth profile passivation different stages.

参考文章(26)
W. Brendle, V. X. Nguyen, A. Grohe, E. Schneiderlöchner, U. Rau, G. Palfinger, J. H. Werner, 20·5% efficient silicon solar cell with a low temperature rear side process using laser‐fired contacts Progress in Photovoltaics. ,vol. 14, pp. 653- 662 ,(2006) , 10.1002/PIP.696
I Romijn, Brett Hallam, Florence Chen, Jason Tan, Jeffrey E Cotter, Arthur Weeber, Relationship between PECVD silicon nitride film composition and surface and edge passivation 22nd European Photovoltaic Solar Energy Conference and Exhibition, Milan, Italy, 3-7 september 2007., 8 p.. ,(2007)
Barbara Terheiden, Heiko Plagwitz, Rolf Brendel, Formation of defects at the amorphous silicon-crystalline silicon interface during annealing 22th European Photovoltaic Solar Energy Conference and Exhibition. pp. 936- 939 ,(2007)
H. Mäckel, R. Lüdemann, Detailed study of the composition of hydrogenated SiNx layers for high-quality silicon surface passivation Journal of Applied Physics. ,vol. 92, pp. 2602- 2609 ,(2002) , 10.1063/1.1495529
S. W. Glunz, D. Biro, S. Rein, W. Warta, Field-effect passivation of the SiO2Si interface Journal of Applied Physics. ,vol. 86, pp. 683- 691 ,(1999) , 10.1063/1.370784