Aminophosphine–palladium(II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactions
作者： Murat Aydemir , Akin Baysal , Ertan Sahin , Bahattin Gumgum , Saim Ozkar
DOI: 10.1016/J.ICA.2011.07.056
关键词: Heck reaction 、 Stereochemistry 、 Coupling reaction 、 Suzuki reaction 、 Amine gas treating 、 Medicinal chemistry 、 Palladium 、 Catalysis 、 Furfurylamine 、 Chemistry 、 Infrared spectroscopy 、 Physical and Theoretical Chemistry 、 Inorganic chemistry 、 Materials Chemistry
摘要: Abstract Reaction of furfurylamine with 1 or 2 equivalents PPh 2 Cl in the presence Et 3 N, proceeds under anaerobic conditions thf to give furfuryl-2-( N -diphenylphosphino)amine, Ph PNHCH -C 4 H O, and , -bis(diphenylphosphino)amine), (Ph P) NCH respectively. The reactions MCl (cod) (M = Pd, Pt; cod = 1,5-cyclooctadiene) Pt(CH ) yield complexes [M(Ph O) ] (M = Pd 1a Pt 1b ), [Pt(Ph (CH ( 1c [M((Ph O)Cl 2a 2b [Pt((Ph O)(CH 2c All compounds were isolated as analytically pure substances characterized by NMR, IR spectroscopy elemental analysis. Representative solid-state structures also determined X-ray single crystal diffraction technique. Furthermore, palladium tested found be highly active catalysts Suzuki coupling Heck reaction affording biphenyls trans -stilbenes,
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sci-hub.se 参考文章(73)
Vladimir V. Grushin, Howard Alper, Activation of Otherwise Unreactive C-Cl Bonds ChemInform. ,vol. 31, pp. 193- 226 ,(1999) , 10.1007/3-540-68525-1_8
Ekkehard Lindner, Markus Mohr, Christiane Nachtigal, Riad Fawzi, Gerald Henkel, Preparation, properties and reactions of metal-containing heterocycles: Part C: tetraazatetraphosphadimolybdacyclophanes: synthesis, isolation, characterization, and X-ray crystal structures Journal of Organometallic Chemistry. ,vol. 595, pp. 166- 177 ,(2000) , 10.1016/S0022-328X(99)00587-2
Handbook of organopalladium chemistry for organic synthesis John Wiley & Sons, Inc.. ,(2002) , 10.1002/0471212466
Homogeneous catalysis with metal phosphine complexes Plenum Press. ,(1983) , 10.1007/978-1-4613-3623-5
Metal-catalyzed cross-coupling reactions Wiley-VCH. ,(2004) , 10.1002/9783527619535
D. Drew, J. R. Doyle, Alan G. Shaver, Cyclic Diolefin Complexes of Platinum and Palladium Inorganic Syntheses, Volume 13. pp. 346- 349 ,(2007) , 10.1002/9780470132449.CH11
E. Costa, P. G. Pringle, M. Ravetz, Richard J. Puddephatt, [(1,2,5,6‐N)‐1,5‐Cyclooctadiene]Dimethyl‐Platinum(II) Inorganic Syntheses, Volume 31. pp. 284- 286 ,(2007) , 10.1002/9780470132623.CH49
Ryōji Noyori, Asymmetric catalysis in organic synthesis ,(1994)
Zhi-Wei Wang, Peng Qiao, Zi-Jia Wang, Chong-Qing Wan, [N-Benzyl-N-(diphenylphosphanylmethyl)pyridin-2-amine]chloridomethylplatinum(II) Acta Crystallographica Section E-structure Reports Online. ,vol. 67, ,(2011) , 10.1107/S1600536810049652
Nikolai A. Bumagin, Victor V. Bykov, Ligandless palladium catalyzed reactions of arylboronic acids and sodium tetraphenylborate with aryl halides in aqueous media Tetrahedron. ,vol. 53, pp. 14437- 14450 ,(1997) , 10.1016/S0040-4020(97)00936-8