Thermodynamics of Ketone + Amine Mixtures. Part III. Volumetric and Speed of Sound Data at (293.15, 298.15, and 303.15) K for 2-Butanone + Aniline, + N-Methylaniline, or + Pyridine Systems†
作者： Iván Alonso , Ismael Mozo , Isaías García de la Fuente , Juan Antonio González , José Carlos Cobos
DOI: 10.1021/JE100472T
关键词: N-Methylaniline 、 Molar volume 、 Thermodynamics 、 Isentropic process 、 Thermal expansion 、 Chemistry 、 Atmospheric pressure 、 Pyridine 、 Aniline 、 Speed of sound
摘要: Densities, ρ, and speeds of sound, u, 2-butanone + aniline, N-methylaniline, or pyridine systems have been measured at (293.15, 298.15, 303.15) K atmospheric pressure using a vibrating-tube densimeter sound analyzer (Anton Paar model DSA-5000). The ρ u values were used to calculate excess molar volumes, VE, the functions 298.15 for speed uE, thermal expansion coefficient, αPE, isentropic compressibility, κSE. VE κSE are both negative magnitudes increase in sequence: aniline < N-methylaniline pyridine. In contrast, uE is positive changes opposite way. Data suggest existence strong interactions between unlike molecules.
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cheric.org参考文章(31)
B. González, A. Domínguez, J. Tojo, Physical properties of the binary systems methylcyclopentane with ketones (acetone, butanone and 2-pentanone) at T = (293.15, 298.15, and 303.15) K. New UNIFAC-VISCO interaction parameters The Journal of Chemical Thermodynamics. ,vol. 38, pp. 707- 716 ,(2006) , 10.1016/J.JCT.2005.08.002
Gérard Douhéret, Michael I. Davis, João Carlos R. Reis, Michael J. Blandamer, Isentropic Compressibilities—Experimental Origin and the Quest for their Rigorous Estimation in Thermodynamically Ideal Liquid Mixtures ChemPhysChem. ,vol. 2, pp. 148- 161 ,(2001) , 10.1002/1439-7641(20010316)2:3<148::AID-CPHC148>3.0.CO;2-J
Toshiharu Takagi, Ultrasonic speeds and thermodynamics of (benzene + aniline) and (chlorobenzene + aniline) under high pressures The Journal of Chemical Thermodynamics. ,vol. 12, pp. 277- 286 ,(1980) , 10.1016/0021-9614(80)90047-6
Katsutoshi Tamura, Sachio Murakami, Speeds of sound, isentropic and isothermal compressibilities, and isochoric heat capacities of {xc-C6H12 + (1 − x)C6H6} from 293.15 to 303.15 K The Journal of Chemical Thermodynamics. ,vol. 16, pp. 33- 38 ,(1984) , 10.1016/0021-9614(84)90072-7
Iván Alonso, Víctor Alonso, Ismael Mozo, Isaías García de la Fuente, Juan Antonio González, José Carlos Cobos, Thermodynamics of ketone+amine mixtures Journal of Molecular Liquids. ,vol. 155, pp. 109- 114 ,(2010) , 10.1016/J.MOLLIQ.2010.05.022
Liyan Su, Haijun Wang, Volumetric properties of dichloromethane with aniline or nitrobenzene at different temperatures: A theoretical and experimental study The Journal of Chemical Thermodynamics. ,vol. 41, pp. 315- 322 ,(2009) , 10.1016/J.JCT.2008.08.013
Jyoti N. Nayak, Mrityunjaya I. Aralaguppi, Udaya S. Toti, Tejraj M. Aminabhavi, Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K Journal of Chemical & Engineering Data. ,vol. 48, pp. 1483- 1488 ,(2003) , 10.1021/JE030147G
A. Lainez, M. M. Rodrigo, Emmerich Wilhelm, J. -P. E. Grolier, Thermodynamics of liquid mixtures containing n-alkanes and strongly polar components: VE and C P E of mixtures with either pyridine or piperidine Journal of Solution Chemistry. ,vol. 21, pp. 49- 65 ,(1992) , 10.1007/BF00648980
George C. Benson, Carl J. Halpin, Andrzej J. Treszczanowicz, Excess volumes and isentropic compressibilities for (2-ethoxyethanol + n-heptane) at 298.15 K The Journal of Chemical Thermodynamics. ,vol. 13, pp. 1175- 1183 ,(1981) , 10.1016/0021-9614(81)90017-3
C. Lesbats, A. Lichanot, Capacites calorifiques de durcisseurs amines et resines epoxydes Thermochimica Acta. ,vol. 109, pp. 317- 329 ,(1987) , 10.1016/0040-6031(87)80028-X