Fractionation of uranium forms as affected by spiked soil treatment and soil type.

作者: A. Z. Mostafa , M. F. Abdel-Sabour , S. M. Lotfy

DOI:

关键词: Iron oxideSoil typeUraniumEnvironmental chemistrySoil scienceCarbonateManganeseSoil classificationChemistryCation-exchange capacityFractionation

摘要: To evaluate the effect of different soil factors on uranium distribution fraction in soil, a U-fractionation experiment was conducted. Different Uranium forms were compared two types (clayey from Mostourd area and sandy collected El-Gabal Al-Asfar area). Also, variation due to treatment (spiking) studied. In case Mostorud clayey initial Uraniumfractions 45.63 % as residual form, 20.69 organically bound 16.36 Manganese iron oxides bound, 9.76% Carbonate 7.41 exchangeable fractions 0.15% water soluble fractions. These varied significantly when spiked with 200 mg / Kg 46.88 %, 23.19 9.97 16.07 3.79% 0.10% for residual, organically, oxide, carbonate, respectively. result showed significant reduction Uranium-ex - increase Uranium-carbonate form application. untreated main Uranium-fractions 57.42% (relatively higher – soil) 16.10 13.78% 7.22 5.23 0.25 The application Uranium/Kg resulted changes Uranium-Fractions follows : 59.26 , 11.27 19.59 6.84 2.90 0.14 organic –iron It could be concluded that solubility depends upon soil’s physicochemical, mineralogical micromorphological properties; nature association; mineralogical, morphological, compositional characteristics uranium-bearing phases.

参考文章(22)
U. Förstner, W. Salomons, Trace metal analysis on polluted sediments Environmental Technology. ,vol. 1, pp. 494- 505 ,(1980) , 10.1080/09593338009384006
R. Johnson, C. M. Wai, B. McVeety, H. Lee, H. Willmes, Uranium in soil around phosphate processing plants in Pocatello, Idaho Bulletin of Environmental Contamination and Toxicology. ,vol. 24, pp. 735- 738 ,(1980) , 10.1007/BF01608181
Zhongwen Wang, Xiao-quan Shan, Shuzhen Zhang, Comparison between fractionation and bioavailability of trace elements in rhizosphere and bulk soils Chemosphere. ,vol. 46, pp. 1163- 1171 ,(2002) , 10.1016/S0045-6535(01)00206-5
T. L. Jones, R. J. Serne, Contaminant Release from Solidified Radioactive Wastes Buried in Unsaturated Sediments: Lysimeter Study Journal of Environmental Quality. ,vol. 24, pp. 1063- 1073 ,(1995) , 10.2134/JEQ1995.00472425002400060004X
M. Iggy Litaor, Uranium isotopes distribution in soils at the Rocky Flats Plant, Colorado Journal of Environmental Quality. ,vol. 24, pp. 314- 323 ,(1995) , 10.2134/JEQ1995.00472425002400020015X
Xingfu Xian, Chemical partitioning of cadmium, zinc, lead, and copper in soils near smelter Journal of Environmental Science and Health Part A-toxic\/hazardous Substances & Environmental Engineering. ,vol. 22, pp. 527- 541 ,(1987) , 10.1080/10934528709375368
R. Calvet, S. Bourgeois, J. J. Msaky, Some Experiments on Extraction of Heavy Metals Present in Soil International Journal of Environmental Analytical Chemistry. ,vol. 39, pp. 31- 45 ,(1990) , 10.1080/03067319008027680
V. A. Vicente-Beckett, C. B. Pascual, C. S. Kwan, R. Beckett, Levels and Distribution of Trace Metals in Sediments of Laguna Lake (Philippines) and its Tributary Rivers International Journal of Environmental Analytical Chemistry. ,vol. 45, pp. 101- 116 ,(1991) , 10.1080/03067319108026980
G. Rauret, R. Rubio, J. F. Lopez-sanchez, E. Casassas, Specific Procedure for Metal Solid Speciation in Heavily Polluted River Sediments International Journal of Environmental Analytical Chemistry. ,vol. 35, pp. 89- 100 ,(1989) , 10.1080/03067318908028382