Three‐coordinate divalent Group 14 element derivatives and related compounds
作者： Isabelle Saur , Sonia Garcia Alonso , Jacques Barrau
DOI: 10.1002/AOC.876
关键词: Chemistry 、 Divalent 、 Group (periodic table) 、 Tin 、 Germanium 、 Stereochemistry 、 Ligand 、 Germane 、 Stannane 、 Cationic polymerization
摘要: This review describes recent work on the synthesis, spectroscopic analysis, structures and investigation of chemical behaviours new subvalent germanium tin compounds supported by β-diketiminato ligand L2 (L2 = NPhC(Me)CHC(Me)NPh), namely divalent species L2(X)M, germane stannane chalcogenones L2(X)MY, heavier Group 14 element transition-metal complexes L2(X)MM′(CO)n cationic germanium–transition-metal [L2Ge+M′(CO)n]. Copyright © 2005 John Wiley & Sons, Ltd.
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