Control of porosity and surface area in alumina. I: Effect of preparation conditions

作者: Y. Huang , A. White , A. Walpole , D.L. Trimm

DOI: 10.1016/S0166-9834(00)80167-0

关键词: PorosimetryMineralogySodium nitrateChemistryPseudoboehmiteChemical engineeringTexture (crystalline)Sodium hydroxideAmmonium hydroxideHydroxideCalcination

摘要: Abstract As part of a study the preparation aluminas controlled porosity and surface area, initial investigations have focused on prepared in absence additives that control texture. The pore size area has been found to be affected significantly by conditions precipitation ageing, largely due interconversion amorphous hydroxide, pseudoboehmite bayerite. Washing drying were small effects texture except comparative experiments which sodium hydroxide was used as precipitant instead ammonium hydroxide. In this case, washing removed residual nitrate enlarged size. effect calcination intermediates affect alumina same manner previously reported.

参考文章(9)
Ulrich Hammon, Michael Kotter, Herstellung von Formkörpern mit definierter Porenstruktur Chemie Ingenieur Technik. ,vol. 56, pp. 455- 463 ,(1984) , 10.1002/CITE.330560607
M JOHNSON, The origin and types of pores in some alumina catalysts Journal of Catalysis. ,vol. 10, pp. 342- 354 ,(1968) , 10.1016/0021-9517(68)90149-8
E. Ruckenstein, The origin of thermodynamic stability of microemulsions Chemical Physics Letters. ,vol. 57, pp. 517- 521 ,(1978) , 10.1016/0009-2614(78)85311-1
D.L. Trimm, A. Stanislaus, The control of pore size in alumina catalyst supports: A review Applied Catalysis. ,vol. 21, pp. 215- 238 ,(1986) , 10.1016/S0166-9834(00)81356-1
Brian Cormack, John J. Freeman, Kenneth S. W. Sing, Porosity of alumina gels prepared from solutions of aluminium nitrate in various alcohols Journal of Chemical Technology & Biotechnology. ,vol. 30, pp. 367- 373 ,(2007) , 10.1002/JCTB.503300144
Ch. Sivaraj, B. Prabhakara Reddy, B. Rama Rao, P. Kanta Rao, Preparation of catalytically active γ-Al2O3 from a basic aluminium succinate precursor precipitated from homogeneous solution Applied Catalysis. ,vol. 24, pp. 25- 35 ,(1986) , 10.1016/S0166-9834(00)81255-5
G. C. Bye, J. G. Robinson, Crystallization processes in aluminium hydroxide gels Kolloid-Zeitschrift und Zeitschrift für Polymere. ,vol. 198, pp. 53- 60 ,(1964) , 10.1007/BF01499454
L. Moscou, G. S. Vlies, Electron microscope investigations on the morphology of aluminium hydroxides Colloid and Polymer Science. ,vol. 163, pp. 35- 41 ,(1959) , 10.1007/BF01511980