Four new water-stable metal-organic frameworks based on diverse metal clusters: Syntheses, structures, and luminescent sensing properties
作者： Ya-Ke Fan , Wen-Yan Zhang , Si-Si Zhang , Yang-Tian Yan , Kai Zhong
DOI: 10.1016/J.JSSC.2018.10.017
关键词: Isophthalic acid 、 Quenching (fluorescence) 、 Crystallography 、 Crystal structure 、 Metal clusters 、 Metal-organic framework 、 Luminescence 、 SBus 、 Materials science 、 Single crystal 、 Physical and Theoretical Chemistry 、 Inorganic chemistry 、 Materials Chemistry 、 Electronic, Optical and Magnetic Materials 、 Condensed matter physics 、 Ceramics and Composites
摘要: Abstract Four new water-stable luminescent metal-organic frameworks (MOFs), namely {[Zn4(L)2(H2O)4(OH)2]·3NMP}n (1), {[Zn3(L)2(H2O)2]·Diox}n (2), {[Cd3(L)2 (H2O)5]·NMP·3H2O}n (3), and {[Pb3(L)2(NMP)2(H2O)]·H2O}n (4), (H3L = 5-(1-(carboxymethyl)pyrazol-3-yl)isophthalic acid; NMP = N-methyl-2-Pyrrolidoneand; Diox = 1,4-Dioxane) have been solvothermally synthesized with different solvents. The single crystal structures of 1–4 reveal that complexes 1 2 form the 2D (3,6)-connected kgd nets based on tetranuclear [Zn4(μ1-COO)2(μ2-COO)4] clusters trinuclear [Zn3(μ1-COO)2(μ2-COO)4] clusters, respectively. Complex 3 displays a net [Cd3(μ1-COO)4(μ2-COO)2] clusters. 4 presents layer rod-shaped SBUs. solid-state luminescence properties water stability these were investigated carefully, showing high selectivity for Fe3+, CrO42−, Cr2O72− via quenching effects low detection limits. probable mechanisms studied in detail.
harvard.edu
elsevier.com
sci-hub.se 参考文章(68)
David J. Tranchemontagne, José L. Mendoza-Cortés, Michael O’Keeffe, Omar M. Yaghi, Secondary building units, nets and bonding in the chemistry of metal–organic frameworks Chemical Society Reviews. ,vol. 38, pp. 1257- 1283 ,(2009) , 10.1039/B817735J
Akbar Bagheri, Mohsen Taghizadeh, Mohammad Behbahani, Ali Akbar Asgharinezhad, Mani Salarian, Ali Dehghani, Homeira Ebrahimzadeh, Mostafa M Amini, None, Synthesis and characterization of magnetic metal-organic framework (MOF) as a novel sorbent, and its optimization by experimental design methodology for determination of palladium in environmental samples Talanta. ,vol. 99, pp. 132- 139 ,(2012) , 10.1016/J.TALANTA.2012.05.030
Daniel Prá, Angelica Bortoluzzi, Luiza Louzada Müller, Liziane Hermes, Jorge André Horta, Sharbel Weidner Maluf, João Antonio Pêgas Henriques, Michael Fenech, Silvia Isabel Rech Franke, Iron intake, red cell indicators of iron status, and DNA damage in young subjects Nutrition. ,vol. 27, pp. 293- 297 ,(2011) , 10.1016/J.NUT.2010.02.001
Yunlong Wu, Guo-Ping Yang, Xiang Zhou, Jiang Li, Yan Ning, Yao-Yu Wang, Three new luminescent Cd(II)-MOFs by regulating the tetracarboxylate and auxiliary co-ligands, displaying high sensitivity for Fe3+ in aqueous solution Dalton Transactions. ,vol. 44, pp. 10385- 10391 ,(2015) , 10.1039/C5DT00492F
Zhiqiang Han, Li Qi, Gangyi Shen, Wei Liu, Yi Chen, Determination of Chromium(VI) by Surface Plasmon Field-Enhanced Resonance Light Scattering Analytical Chemistry. ,vol. 79, pp. 5862- 5868 ,(2007) , 10.1021/AC062453D
Clara S. B. Gomes, Pedro T. Gomes, M. Teresa Duarte, Roberto E. Di Paolo, António L. Maçanita, Maria José Calhorda, Synthesis, structure, and photophysical characterization of blue-green luminescent zinc complexes containing 2-iminophenanthropyrrolyl ligands. Inorganic Chemistry. ,vol. 48, pp. 11176- 11186 ,(2009) , 10.1021/IC901519S
Oleg V. Dolomanov, Luc J. Bourhis, Richard J. Gildea, Judith A. K. Howard, Horst Puschmann, OLEX2: a complete structure solution, refinement and analysis program Journal of Applied Crystallography. ,vol. 42, pp. 339- 341 ,(2009) , 10.1107/S0021889808042726
Ji-Na Hao, Bing Yan, A water-stable lanthanide-functionalized MOF as a highly selective and sensitive fluorescent probe for Cd2+ Chemical Communications. ,vol. 51, pp. 7737- 7740 ,(2015) , 10.1039/C5CC01430A
Cheng-Xiong Yang, Hu-Bo Ren, Xiu-Ping Yan, Fluorescent Metal–Organic Framework MIL-53(Al) for Highly Selective and Sensitive Detection of Fe3+ in Aqueous Solution Analytical Chemistry. ,vol. 85, pp. 7441- 7446 ,(2013) , 10.1021/AC401387Z
Ji-Yong Zou, Hong-Ling Gao, Wei Shi, Jian-Zhong Cui, Peng Cheng, Auxiliary ligand-assisted structural diversities of three metal–organic frameworks with potassium 1H-1,2,3-triazole-4,5-dicarboxylic acid: syntheses, crystal structures and luminescence properties CrystEngComm. ,vol. 15, pp. 2682- 2687 ,(2013) , 10.1039/C3CE26854C