Studies on thermodynamic properties of (a hydrocarbon + a branched chain ether) mixtures
作者： U Domańska , S Malanowski
DOI: 10.1016/S0378-3812(99)00083-7
关键词: Non-random two-liquid model 、 Tetradecane 、 UNIQUAC 、 Ether 、 Organic chemistry 、 Dodecane 、 Analytical chemistry 、 Alkane 、 Decane 、 Chemistry 、 Octane
摘要: Abstract The solid–liquid equilibrium, SLE, has been measured for {a hydrocarbon (C18–C28)+methyl 1,1-dimethylethyl ether (MTBE), or ethyl (ETBE)} mixtures from 280 K to the melting temperature of hydrocarbon. Experimental solubilities are compared with values calculated by means Wilson, UNIQUAC and NRTL equations utilizing parameters taken SLE. liquid–liquid LLE, {water+(ETBE), methyl 1,1-dimethylpropyl (MTAE), (ETAE)} 300 360 K. mutual solubility in binary systems (heptane, 1-heptene, toluene+MTBE, ETBE, MTAE) range 273 298 measured. All these have found be homogenous. excess molar volumes, VmE, at temperatures 298.15 308.15 (hexane, octane, decane, dodecane, tetradecane, hexadecane), cyclohexane 1-heptyne+a branched chain (ETBE)}. volumes all except 1-heptyne positive over whole composition range. experimental results correlated Prigogine–Flory–Patterson (PFP) theory.
elsevier.com
sci-hub.se 参考文章(26)
P. Venkatesu, U. Domańska, SOLUBILITY OF N-ALKANES IN ETHYL TERT-BUTYL ETHER Polish Journal of Chemistry. ,vol. 72, pp. 1981- 1993 ,(1998)
Teresa Treszczanowicz, Application of the flory and sanchez-lacombe theories to the excess enthalpy and excess volume of ether + hydrocarbon systems Thermochimica Acta. ,vol. 160, pp. 253- 266 ,(1990) , 10.1016/0040-6031(90)80265-Z
Paolo Berti, Luciano Lepori, Enrico Matteoli, Excess volumes of cyclohexane + a linear ether at 298.15 K Fluid Phase Equilibria. ,vol. 44, pp. 285- 294 ,(1989) , 10.1016/0378-3812(89)80058-5
R. F. Weimer, J. M. Prausnitz, Complex Formation between Carbon Tetrachloride and Aromatic Hydrocarbons Journal of Chemical Physics. ,vol. 42, pp. 3643- 3644 ,(1965) , 10.1063/1.1695773
M. Witek, A. Gołdon, T. Hofman, U. Domańska, Densities and Excess Volumes of Methyl 1,1-Dimethylpropyl Ether + Benzene, or Cyclohexane, or an Alkane (C6−C16) at 298.15 K Journal of Chemical & Engineering Data. ,vol. 42, pp. 60- 63 ,(1997) , 10.1021/JE960241F
Urszula Domańska, Solubility of n-alkanols (C16,C18,C20) in binary solvent mixtures Fluid Phase Equilibria. ,vol. 46, pp. 223- 248 ,(1989) , 10.1016/0378-3812(89)80037-8
Shemin Zhu, Shubao Shen, George C. Benson, Benjamin C.-Y. Lu, Excess enthalpies of (methyl 1,1-dimethylpropyl ether + an n-alkane) at the temperature 298.15 K The Journal of Chemical Thermodynamics. ,vol. 26, pp. 35- 39 ,(1994) , 10.1006/JCHT.1994.1017
W. Mier, R.N. Lichtenthaler, A.H. Roux, J.-P.E. Grolier, Excess molar heat capacities CEp,m and excess molar volumes VEm of {x1CH3(CH2)5CH3 + x2CH3C(CH3)2CH2CH(CH3)CH3 + x3CH3C(CH3)2OC2H5 + (1 - x1 - x2 - x3)C2H5OH}(l) I. Binary and quaternary mixtures The Journal of Chemical Thermodynamics. ,vol. 26, pp. 1323- 1334 ,(1994) , 10.1006/JCHT.1994.1151
T. M. Letcher, R. C. Baxter, Application of the Prigogine-Flory-Patterson theory part I. Mixtures ofn-alkanes with bicyclic compounds, benzene, cyclohexane andn-hexane Journal of Solution Chemistry. ,vol. 18, pp. 65- 80 ,(1989) , 10.1007/BF00646083
D. Zikmundová, J. Matouš, J.P. Novák, V. Kubíček, J. Pick, Liquid—liquid and vapour—liquid equilibria in the system methyl tert-butyl ether + tetrahydrofuran + water Fluid Phase Equilibria. ,vol. 54, pp. 93- 110 ,(1990) , 10.1016/0378-3812(90)85073-J