2-Thienylcarboxylato and 2-thienylthiocarboxylato ligands bonded to MM quadruple bonds (M = Mo or W): a comparison of ground state, spectroscopic and photoexcited state properties.
作者： Brian G. Alberding , Malcolm H. Chisholm , Yi-Hsuan Chou , Yagnaseni Ghosh , Terry L. Gustafson
DOI: 10.1021/IC901607U
关键词: Toluene 、 Physical chemistry 、 Chemistry 、 Quadruple bond 、 Photochemistry 、 State (functional analysis) 、 Ground state
摘要: The compounds M2(TiPB)2(OSC-2-Th)2 have been prepared from the reactions between M2(TiPB)4 and Th-2-COSH (2 equiv) in toluene solution, where M = Mo (Mo2ThCOS) or W (W2ThCOS), TiPB 2,4,6-triisopr...
acs.org
sci-hub.se 参考文章(19)
Robert G. Parr, Density-functional theory of atoms and molecules ,(1989)
Toshihiro Nakayama, Yutaka Amijima, Kazuyasu Ibuki, Kumao Hamanoue, Construction of a subpicosecond double-beam laser photolysis system utilizing a femtosecond Ti:sapphire oscillator and three Ti:sapphire amplifiers (a regenerative amplifier and two double passed linear amplifiers), and measurements of the transient absorption spectra by a pump-probe method Review of Scientific Instruments. ,vol. 68, pp. 4364- 4371 ,(1997) , 10.1063/1.1148398
A. P. Sattelberger, D. J. Santure, J. C. Huffman, Synthesis and properties of ditungsten(II) tetracarboxylates Inorganic Chemistry. ,vol. 24, pp. 371- 378 ,(1985)
Malcolm H. Chisholm, Factors influencing the reductive cleavage of C-X multiple bonds in their reactions with metal-metal multiple bonds (X = C, N, O, S) Chemical Record. ,vol. 1, pp. 12- 23 ,(2001) , 10.1002/1528-0691(2001)1:1<12::AID-TCR4>3.0.CO;2-5
Mikhail V. Barybin, Malcolm H. Chisholm, Nathan J. Patmore, Randall E. Robinson, Namrata Singh, Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-carboethoxy-2-carboxylatoazulene ligands. Chemical Communications. pp. 3652- 3654 ,(2007) , 10.1039/B708746B
Malcolm H. Chisholm, Pi-Tai Chou, Yi-Hsuan Chou, Yagnaseni Ghosh, Terry L. Gustafson, Mei-Lin Ho, Preparations and Photophysical Properties of Fused and Nonfused Thienyl Bridged MM (M = Mo or W) Quadruply Bonded Complexes Inorganic Chemistry. ,vol. 47, pp. 3415- 3425 ,(2008) , 10.1021/IC800090N
Burkhard Miehlich, Andreas Savin, Hermann Stoll, Heinzwerner Preuss, Results obtained with the correlation energy density functionals of becke and Lee, Yang and Parr Chemical Physics Letters. ,vol. 157, pp. 200- 206 ,(1989) , 10.1016/0009-2614(89)87234-3
Ralph G. Pearson, HARD AND SOFT ACIDS AND BASES Journal of the American Chemical Society. ,vol. 85, pp. 3533- 3539 ,(1963) , 10.1021/JA00905A001
F. Albert Cotton, Elizabeth A. Hillard, Carlos A. Murillo, Hong-Cai Zhou, After 155 Years, A Crystalline Chromium Carboxylate with a Supershort Cr−Cr Bond Journal of the American Chemical Society. ,vol. 122, pp. 416- 417 ,(2000) , 10.1021/JA993755I
Malcolm H. Chisholm, Nathan J. Patmore, Electronic coupling in 1,4-(COS)2C6H4 linked MM quadruple bonds (M = Mo, W): the influence of S for O substitution Dalton Transactions. pp. 3164- 3169 ,(2006) , 10.1039/B600983B