Thermal behavior of Zn and Cd complexes intercalated into γ-zirconium phosphate: Synthesis and physical–chemical characterization
作者： Carla Ferragina , Romolo Di Rocco , Sabrina Foglia , Lucantonio Petrilli
DOI: 10.1016/J.COLSURFA.2006.07.015
关键词: Inorganic chemistry 、 Thermal stability 、 Ligand 、 Metal 、 Chemistry 、 Zirconium phosphate 、 Phosphate 、 Diamine 、 Intercalation (chemistry) 、 Zinc
摘要: Abstract Intercalation compounds such as zinc and cadmium diamines complexes intercalated into the inorganic layered ion-exchanger γ-zirconium phosphate have been synthesized characterized. The diamine content inside host matrix depends on ligand size; “in situ” formed depend metal ion exchanged. Only in case of 2,2′-bipyridyl amine, after cation exchange with Zn Cd, is an increase interlayer distance observed energy variations from IR measurements. All prepared materials maintained thermal stability up to about 400 °C. At a higher temperature combustion occurs depending size.
elsevier.com
sci-hub.se 参考文章(28)
C. Ferragina, P. Cafarelli, R. Di Rocco, Compounds of γ-zirconium hydrogen phosphate with cadmium ions: Synthesis, thermal behavior and X-ray characterization Thermochimica Acta. ,vol. 363, pp. 81- 91 ,(2000) , 10.1016/S0040-6031(00)00601-8
Abraham Clearfield, John M. Kalnins, On the mechanism of ion exchange in zirconium phosphates—XIII: Exchange of some divalent transition metal ions on α-zirconium phosphate Journal of Inorganic and Nuclear Chemistry. ,vol. 38, pp. 849- 852 ,(1976) , 10.1016/0022-1902(76)80369-7
Юрий Иванович Долженко, Т Інабэ, Ю Маруяма, In Situ X-Ray Observation on the Intercalation of Weak Interaction Molecules into Perovskite-Type Layered Crystals (C9H19NH3)2PbI4 and (C10H21NH3)2CdCl4 Bulletin of the Chemical Society of Japan. ,vol. 59, pp. 563- 567 ,(1986) , 10.1246/BCSJ.59.563
C. Ferragina, P. Cafarelli, R. Di Rocco, M.A. Massucci, Thermal behaviour of γ-titanium phosphate-phenanthroline intercalation compound exchanged with silver and other transition metal ions☆ Thermochimica Acta. pp. 507- 521 ,(1995) , 10.1016/0040-6031(95)02534-0
Carla Ferragina, Maria A. Massucci, Anthony A. G. Tomlinson, Pillar chemistry. Part 5. Intercalation of 2,2′-bipyridine, 1,10-phenanthroline, and 2,9-dimethyl-1,10-phenanthroline into γ-zirconium phosphate and formation of interlayer copper(II) complexes Journal of The Chemical Society-dalton Transactions. pp. 1191- 1196 ,(1990) , 10.1039/DT9900001191
K. J. Chao, T. C. Chang, S. Y. Ho, Intercalation and oxidative polymerization of aniline in zirconium phosphates Journal of Materials Chemistry. ,vol. 3, pp. 427- 428 ,(1993) , 10.1039/JM9930300427
FE Men�ndez, Ar�nzazu Espina, Camino Trobajo, Jos� R. Garc�a, Julio Rodr�guez, Intercalation ofn-alkylamines into α-titanium phosphate from aqueous solutions Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 15, pp. 215- 230 ,(1994) , 10.1007/BF00709068
Marco Arfelli, Giulia Mattogno, Carla Ferragina, Maria Antonietta Massucci, XPS characterization of γ -zirconium phosphate and of some of its intercalation compounds. A comparison with the α-zirconium phosphate analogues Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 11, pp. 15- 27 ,(1991) , 10.1007/BF01073680
C. Ferragina, R. Di Rocco, L. Petrilli, Thermal behavior of zinc γ-zirconium phosphate intercalation compounds Journal of Thermal Analysis and Calorimetry. ,vol. 81, pp. 67- 74 ,(2005) , 10.1007/S10973-005-0747-X
U. Costantino, A. La Ginestra, On the existence of pyrophosphates of tetravalent metals having a layered structure Thermochimica Acta. ,vol. 58, pp. 179- 189 ,(1982) , 10.1016/0040-6031(82)87080-9