Vibrational properties of and short range order in superionic glasses AgPO3−AgX (X = I, Br, Cl)
作者： J Malugani
DOI: 10.1016/0167-2738(84)90071-7
关键词: Chemistry 、 Ion 、 Short range order 、 Linear relation 、 Raman scattering 、 Halide 、 Analytical chemistry 、 Line (formation) 、 Stereochemistry 、 Cluster (physics)
摘要: Abstract Raman scattering measurements are reported for different glasses containing silver halides. The high frequency (Δ v > 250 cm -1 ) study implies that the interactions between phosphate network and halide solutes very weak. Area of two low-frequency bands ( have shown that: (i) low band (∼60 is only correlated to all Ag + oscillations; (ii) higher shifts from 115 (AgI) 135 (AgBr) 190 (AgCl) its integrated intensity in linear relation AgX concentration. mode has been assigned symmetric vibrations involving both X - ions line αAgI. A local cluster model tetrahedral (AgX) n species proposed each glass.
elsevier.com
sci-hub.se 参考文章(14)
J.P. Malugani, R. Mercier, B. Fahys, G. Robert, Ionic conductivity of and Raman spectroscopy investigation in binary oxosalts (1 − x)AgPO3xAg2SO4 glasses Journal of Solid State Chemistry. ,vol. 45, pp. 309- 316 ,(1982) , 10.1016/0022-4596(82)90176-1
Aldo Magistris, Gaetano Chiodelli, Alberto Schiraldi, Formation of high conductivity glasses in the system AgIAg2OB2O3 Electrochimica Acta. ,vol. 24, pp. 203- 208 ,(1979) , 10.1016/0013-4686(79)80025-0
G. L. Bottger, C. V. Damsgard, Raman Scattering in Wurtzite‐Type AgI Crystals Journal of Chemical Physics. ,vol. 57, pp. 1215- 1218 ,(1972) , 10.1063/1.1678379
Tsutomu Minami, Kazuhiro Imazawa, Masami Tanaka, Formation region and characterization of superionic conducting glasses in the systems AgIAg2OMxOy Journal of Non-crystalline Solids. ,vol. 42, pp. 469- 476 ,(1980) , 10.1016/0022-3093(80)90045-9
S. Geller, Low-temperature phases of the solid electrolyte RbAg 4 I 5 Physical Review B. ,vol. 14, pp. 4345- 4355 ,(1976) , 10.1103/PHYSREVB.14.4345
Gerald Burns, F. H. Dacol, M. W. Shafer, Results from Raman spectra of the superionic conductor AgI Physical Review B. ,vol. 16, pp. 1416- 1425 ,(1977) , 10.1103/PHYSREVB.16.1416
J.P. Malugani, A. Wasniewski, M. Doreau, G. Robert, R. Mercier, Conductivite electrique et spectres de diffusion raman des verres mixtes AgPO3 − MI2 AVEC M = Cd, Hg, Pb. Correlation entre conductivite et structure Materials Research Bulletin. ,vol. 13, pp. 1009- 1016 ,(1978) , 10.1016/0025-5408(78)90165-4
R.J. Cava, F. Reidinger, B.J. Wuensch, Single-crystal neutron-diffraction study of AgI between 23° and 300°C Solid State Communications. ,vol. 24, pp. 411- 416 ,(1977) , 10.1016/0038-1098(77)91306-0
Alberto Schiraldi, AgIAg oxysalt high conductivity glasses: a tentative approach to their structure Electrochimica Acta. ,vol. 23, pp. 1039- 1043 ,(1978) , 10.1016/0013-4686(78)85011-7
David A. Gallagher, Miles V. Klein, Raman scattering studies in the solid electrolytes of the RbAg4I5family Physical Review B. ,vol. 19, pp. 4282- 4291 ,(1979) , 10.1103/PHYSREVB.19.4282