Polymer-bound photosensitizing catalysts

作者: Erich C. Blossey , Douglas C. Neckers , A. Paul Schaap

DOI:

关键词: NucleophileMoleculeSubstitution reactionLeaving groupChemical reactionPolymer chemistryHeterogeneous catalysisPhotochemistryCatalysisReagentChemistry

摘要: Polymer-bound photosensitizing catalysts are effective in the heterogeneous catalysis of various photosensitized chemical reactions, such as photooxidation photodimerization and photocycloaddition thereafter readily separated from reaction medium products by simple filtration. The polymer-bound comprise nucleophilic displacement product (A) a polymeric material having attached thereto an available leaving group which is capable being displaced with reagent (B) catalytic compound containing its molecule nucleophile displacing to reaction.