Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex

作者: Keying Ding , Shi Xu , Keshav Paudel , Bedraj Pandey , Oleksandr Hietsoi

DOI: 10.1021/ACS.ORGANOMET.0C00727

关键词: Combinatorial chemistryPrimary (chemistry)Amine synthesisCobaltCatalysisImineChemistry

摘要: Switchable imine and amine synthesis catalyzed by a tripodal ligand-supported well-defined cobalt complex is presented herein. A large variety of primary alcohols amines were selectively conver...

参考文章(49)
A. J. A. Watson, J. M. J. Williams, The Give and Take of Alcohol Activation Science. ,vol. 329, pp. 635- 636 ,(2010) , 10.1126/SCIENCE.1191843
Robin J. Hamilton, Steven H. Bergens, An Unexpected Possible Role of Base in Asymmetric Catalytic Hydrogenations of Ketones. Synthesis and Characterization of Several Key Catalytic Intermediates Journal of the American Chemical Society. ,vol. 128, pp. 13700- 13701 ,(2006) , 10.1021/JA065460S
C. Gunanathan, D. Milstein, Applications of acceptorless dehydrogenation and related transformations in chemical synthesis. Science. ,vol. 341, pp. 1229712- 1229712 ,(2013) , 10.1126/SCIENCE.1229712
Min Serk Kwon, Sungjin Kim, Sungho Park, William Bosco, Ravi Kumar Chidrala, Jaiwook Park, One-pot synthesis of imines and secondary amines by Pd-catalyzed coupling of benzyl alcohols and primary amines. Journal of Organic Chemistry. ,vol. 74, pp. 2877- 2879 ,(2009) , 10.1021/JO8026609
Graham E. Dobereiner, Robert H. Crabtree, Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis. Chemical Reviews. ,vol. 110, pp. 681- 703 ,(2010) , 10.1021/CR900202J
Christian A. Sandoval, Takeshi Ohkuma, Kilian Muñiz, Ryoji Noyori, Mechanism of Asymmetric hydrogenation of ketones catalyzed by BINAP/1,2-diamine-ruthenium(II) complexes Journal of the American Chemical Society. ,vol. 125, pp. 13490- 13503 ,(2003) , 10.1021/JA030272C
Kamaluddin Abdur-Rashid, Sean E. Clapham, Alen Hadzovic, Jeremy N. Harvey, Alan J. Lough, Robert H. Morris, Mechanism of the hydrogenation of ketones catalyzed by trans-dihydrido(diamine)ruthenium II complexes. Journal of the American Chemical Society. ,vol. 124, pp. 15104- 15118 ,(2002) , 10.1021/JA016817P
Tao Yan, Ben L Feringa, Katalin Barta, Iron catalysed direct alkylation of amines with alcohols Nature Communications. ,vol. 5, pp. 5602- ,(2014) , 10.1038/NCOMMS6602
Biswajit Saha, S. M. Wahidur Rahaman, Prosenjit Daw, Gargi Sengupta, Jitendra K. Bera, Metal-ligand cooperation on a diruthenium platform: selective imine formation through acceptorless dehydrogenative coupling of alcohols with amines. Chemistry: A European Journal. ,vol. 20, pp. 6542- 6551 ,(2014) , 10.1002/CHEM.201304403